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Durability indicatives of hydrogel for agricultural and forestry use in saline conditions
Journal of Arid Environments ( IF 2.7 ) Pub Date : 2021-09-06 , DOI: 10.1016/j.jaridenv.2021.104622
Carla Danielle Vasconcelos do Nascimento 1 , Judith Pessoa de Andrade Feitosa 2 , Robert Simmons 3 , Carlos Tadeu dos Santos Dias 1 , Ícaro Vasconcelos do Nascimento 1 , Jaedson Cláudio Anunciato Mota 1 , Mirian Cristina Gomes Costa 1
Affiliation  

This research tested the hypothesis that the interaction between time and salinity reduces the water absorption potential of a hydrogel – Poly (Acrylamide-co-Potassium Acrylate) and influence the degradation of residual acrylamide monomer. The experimental design was completely randomized split-plot with four replications. The treatments were time periods (30, 60, 90 and 120 days) and levels of salinity of the hydrating solution (distilled water = 0.003, 0.5; 1.5; 3.0 and 6.0 dS m−1). Swelling, hydrogel composition, and residual acrylamide monomer concentration were evaluated. The hydrogel showed lowest water absorption potential (8.1 g g−1) in a saline solution of 4.20 dS m−1 after 120 days. The C/N ratio of the hydrogel increased by up to 47% in a hydrating solution with an EC of 4.4 dS m−1 at 120 days. Additionally, there was an observed shift in the wavelength of methylene, amide, and acrylate bands, that indicates degradation. Residual acrylamide monomer concentration was <0.5 mg g−1 (safe for agricultural use). After 120 days up to 85% of the residual acrylamide monomer was degraded. About the water absorption potential, the results suggest that under semi-arid conditions hydrogel durability for forestry and crops applications may be impaired by the salinity of the hydrating solution.



中文翻译:

盐水条件下农业和林业用水凝胶的耐久性指标

该研究检验了以下假设:时间和盐度之间的相互作用会降低水凝胶 - 聚(丙烯酰胺-- 丙烯酸钾)的吸水潜力,并影响残留丙烯酰胺单体的降解。实验设计是完全随机的裂区,重复四次。处理是时间段(30、60、90 和 120 天)和水合溶液的盐度水平(蒸馏水 = 0.003、0.5;1.5;3.0 和 6.0 dS m -1)。评估了溶胀、水凝胶组成和残留丙烯酰胺单体浓度。水凝胶在 4.20 dS m -1的盐水溶液中表现出最低的吸水潜力(8.1 g g -1120 天后。在 120 天时,水凝胶的 C/N 比在 EC 为 4.4 dS m -1的水合溶液中增加了 47% 。此外,观察到亚甲基、酰胺和丙烯酸酯波段的波长发生变化,这表明降解。残留的丙烯酰胺单体浓度<0.5 mg g -1(农业使用安全)。120 天后,多达 85% 的残留丙烯酰胺单体被降解。关于吸水潜力,结果表明,在半干旱条件下,水凝胶对林业和作物应用的耐久性可能会受到水合溶液盐度的影响。

更新日期:2021-09-06
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