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Heterogeneous NiFeCoP/NF Nanorods as a Bifunctional Electrocatalyst for Efficient Water Electrolysis
ChemCatChem ( IF 4.5 ) Pub Date : 2021-09-03 , DOI: 10.1002/cctc.202100981
Jianmei Cen 1 , Liyan Wu 1 , Yanfei Zeng 1 , Asad Ali 1 , Yuqing Zhu 1 , Pei Kang Shen 1
Affiliation  

Electrocatalysis: Heterogeneous trimetallic phosphide (Ni2P−Fe2P−Co2P−Ni5P4) nanorods derived from an NiFe LDH@ZIF-67 precatalyst on Ni foam (NiFeCoP/NF) as self-supported electrodes for water electrolysis are reported. The enhanced OER/HER performances for NiFeCoP/NF electrode was achieved by improving the quantity and quality of active sites, facilitating the release of O2/H2 bubbles, enhancing conductivity and electron transfer. Moreover, the water-alkali electrolyzer assembled by NiFeCoP/NF as both anode and cathode only needed 1.564 V to deliver 30 mA cm−2 with an excellent stability.
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中文翻译:

多相 NiFeCoP/NF 纳米棒作为高效水电解的双功能电催化剂

催化:多相三金属磷化物 (Ni 2 P−Fe 2 P−Co 2 P−Ni 5 P 4 ) 纳米棒源自 NiFe LDH@ZIF-67 预催化剂在泡沫镍 (NiFeCoP/NF) 上作为水电解的自支撑电极被报道。NiFeCoP/NF 电极的 OER/HER 性能增强是通过提高活性位点的数量和质量、促进 O 2 /H 2气泡的释放、增强电导率和电子转移来实现的。此外,由NiFeCoP/NF组装作为阳极和阴极的水碱电解槽仅需1.564 V即可提供30 mA cm -2且具有优异的稳定性。
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更新日期:2021-11-08
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