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Selective C(sp3)–H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2 as a sustainable oxidant
Green Chemistry ( IF 9.8 ) Pub Date : 2021-08-18 , DOI: 10.1039/d1gc02670d
Yongqiang Zhang 1 , Yunhe Jin 1 , Lifang Wang 1 , Qingqing Zhang 1 , Changgong Meng 1 , Chunying Duan 1
Affiliation  

The visible light-induced metal-free C(sp3)–H phenanthridinylation of simple alkanes with isonitrile is developed with H2O2 as a terminal green oxidant. This reaction features good yields and selectivities, mild conditions, and a broad substrate scope with gaseous alkanes involved, allowing practical access to valuable alkyl-substituted phenanthridine derivatives.

中文翻译:

简单烷烃的选择性 C(sp3)–H 活化:以 H2O2 作为可持续氧化剂的可见光诱导无金属合成菲啶

简单烷烃与异腈的可见光诱导的无金属 C(sp 3 )-H 菲啶化反应是用 H 2 O 2作为末端绿色氧化剂开发的。该反应具有良好的产率和选择性、温和的条件和广泛的底物范围,涉及气态烷烃,可以实际获得有价值的烷基取代菲啶衍生物。
更新日期:2021-09-01
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