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Photoconductivity properties of silver-doped zinc oxide films
Applied Physics A ( IF 2.7 ) Pub Date : 2021-09-01 , DOI: 10.1007/s00339-021-04806-0
R. Hovsepyan 1, 2 , N. Aghamalyan 1, 2 , A. Poghosyan 1 , S. Petrosyan 1, 2 , Y. Kafadaryan 1, 2 , O. Ayvazyan 2 , V. Harutyunyan 2
Affiliation  

The transient photoconductivity of as-deposited and annealed in air 0.27 at.% silver-doped zinc oxide films (Ag:ZnO) coated on sapphire substrates by e-beam evaporation method was measured in the dark (σd) and under light from a solar simulator (σph) at temperatures 8, 12, and 32 °C. In comparison with as-deposited Ag:ZnO film, the annealed film exhibits lower photoresponse which decreases and becomes slower as the temperature increases from 8 to 32 °C. The ln σd versus 1/T plots of the as-deposited and annealed samples revealed thermally-activated process in the range of 5–60 °C for σd with an activation energy of 1.4 eV and 0.8 eV, respectively. Furthermore, σd and σph were measured in the frequency range of 10–35 × 106 s−1 at room temperature. σd of the as-deposited film is frequency independent, while σd of the annealed film exhibits two different conduction mechanisms; one dominates in the low-frequency region as conduction via delocalized states, and the other is the polaron mechanism, which is activated at higher frequencies (ω > 190 × 103 s−1). The frequency dependences of σph of the as-deposited and annealed films obey the Drude model of conductivity.



中文翻译:

掺银氧化锌薄膜的光电导性能

通过电子束蒸发法涂覆在蓝宝石衬底上的 0.27 at.% 掺银氧化锌膜 (Ag:ZnO) 在空气中沉积和退火的瞬态光电导率在黑暗 ( σ d ) 和来自温度为8、12和 32 °C 的太阳模拟器 ( σ ph )。与沉积时的 Ag:ZnO 薄膜相比,退火薄膜表现出较低的光响应,随着温度从 8°C 增加到 32°C,这种光响应会降低并变得更慢。沉积态和退火态样品的 ln σ d与 1/ T曲线图显示σ d在 5–60 °C 范围内的热激活过程活化能分别为 1.4 eV 和 0.8 eV。此外,在室温下在10–35 × 10 6  s -1的频率范围内测量了σ dσ phσ d的所沉积的膜是与频率无关的,而σ d退火膜表现出两种不同的传导机制; 一种在低频区域通过离域状态作为传导占主导地位,另一种是极化子机制,它在较高频率下被激活(ω  > 190 × 10 3  s -1)。σ ph的频率相关性 沉积态和退火态的薄膜遵循德鲁德电导率模型。

更新日期:2021-09-01
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