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Measurements and Modeling of Physicochemical Properties of Pure and Binary Mixtures Containing 1,2-Dimethoxyethane and Some Alcohols
Journal of Chemical & Engineering Data ( IF 2.6 ) Pub Date : 2021-08-31 , DOI: 10.1021/acs.jced.1c00131
Nihelle Lamia Benkelfat-Seladji 1 , Faiza Ouaar 1 , Ariel Hernández 2 , Natalia Muñoz-Rujas 3 , Indra Bahadur 4 , Nouria Chiali-Baba Ahmed 1 , Eduardo Montero 3 , Latifa Negadi 1, 5
Affiliation  

In this paper, experimental values of densities, speeds of sound, and refractive indices in a temperature range of 293.15–323.15 K have been measured as a function of composition for the binary liquid mixtures of 1,2-dimethoxyethane with alcohols such as methanol, propan-1-ol, propan-2-ol, and butan-2-ol. From these experimental values, excess/derived properties such as excess molar volume, isentropic compressibility, deviation in isentropic compressibility, and deviation in the refractive index have been calculated. Excess/derived properties have been correlated using the Redlich–Kister equation and physicochemical properties modeled using the cubic plus association equation of state for pure and binary mixtures. The results are interpreted with respect to possible molecular interactions between components.

中文翻译:

含有 1,2-二甲氧基乙烷和一些醇的纯混合物和二元混合物的物理化学性质的测量和建模

在本文中,密度、声速和折射率的实验值在 293.15-323.15 K 的温度范围内被测量为 1,2-二甲氧基乙烷与醇(如甲醇)的二元液体混合物的组成函数。丙烷-1-醇、丙-2-醇和丁-2-醇。根据这些实验值,计算了过量/衍生的特性,例如过量摩尔体积、等熵压缩率、等熵压缩率偏差和折射率偏差。使用 Redlich-Kister 方程和使用纯和二元混合物的三次加联合状态方程建模的物理化学特性已将过量/衍生特性相关联。根据组分之间可能的分子相互作用来解释结果。
更新日期:2021-09-09
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