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Silver ion loaded 3-aminopropyl trimethoxysilane -modified Fe3O4 nanoparticles for the fabrication of carrageenan-based active packaging films
Colloids and Surfaces B: Biointerfaces ( IF 5.8 ) Pub Date : 2021-08-30 , DOI: 10.1016/j.colsurfb.2021.112085
Shahab Saedi 1 , Mastaneh Shokri 1 , Ruchir Priyadarshi 1 , Jong-Whan Rhim 1
Affiliation  

Fe3O4 nanoparticle loaded with silver ion was prepared as a more efficient, safer, and less environmentally hazardous silver-based antibacterial nanomaterial. The Fe3O4 nanoparticle was modified using 3-aminopropyl trimethoxysilane (APTMS) to enhance the silver ion adsorption capacity and antibacterial activity. Silver ions were adsorbed on pristine Fe3O4 and Fe3O4@NH2 to enhance antibacterial activity. Energy dispersive spectroscopy (EDS) results showed that Fe3O4 adsorbed 2.74 wt% of Ag, whereas Fe3O4@NH2 adsorbed 9.88 wt%. Pristine Fe3O4NP, silver ion loaded Fe3O4 (Fe3O4-Ag), and silver ion loaded Fe3O4@NH2 (Fe3O4@NH2-Ag) were used to manufacture carrageenan-based composite films. Compared with Fe3O4-Ag, Fe3O4@NH2-Ag exhibited stronger antimicrobial activity against E. coli (8.82 vs. 5.02 log reduction) and L. monocytogenes (10.09 vs. 3.93 log reduction). While the addition of Fe3O4 significantly reduced the WCA of the carrageenan films from 61.1 ± 5.4 ° to 37.2 ± 2.1 °, the additions of Fe3O4-Ag and Fe3O4@NH2-Ag reduced the WCA of the film to a lesser extent (56.9 ± 4.6 ° and 56.9 ± 4.6 °, respectively). Fe3O4NP also improved the thermal stability of carrageenan over Fe3O4@NH2-Ag (22 °C vs. 13 °C) and UV blocking properties (T280, 0.1 ± 0.0 % vs. 3.3 ± 1.5 %).



中文翻译:

负载银离子的 3-氨基丙基三甲氧基硅烷修饰的 Fe3O4 纳米粒子用于制备角叉菜胶基活性包装膜

负载银离子的Fe 3 O 4纳米颗粒被制备为一种更有效、更安全、对环境危害更小的银基抗菌纳米材料。使用3-氨基丙基三甲氧基硅烷(APTMS)对Fe 3 O 4纳米颗粒进行改性,以提高银离子吸附能力和抗菌活性。银离子吸附在原始的 Fe 3 O 4和 Fe 3 O 4 @NH 2 上以增强抗菌活性。能量色散谱 (EDS) 结果表明 Fe 3 O 4吸附了 2.74 wt% 的 Ag,而 Fe 3 O 4@NH 2吸附了9.88wt %。使用原始 Fe 3 O 4 NP、负载银离子的 Fe 3 O 4 (Fe 3 O 4 -Ag) 和负载银离子的 Fe 3 O 4 @NH 2 (Fe 3 O 4 @NH 2 -Ag) 来制造卡拉胶基复合薄膜。与 Fe 3 O 4 -Ag相比,Fe 3 O 4 @NH 2 -Ag 对大肠杆菌(8.82 对 5.02 log 减少)和单核细胞增生李斯特菌表现出更强的抗菌活性(10.09 与 3.93 对数减少)。Fe 3 O 4 的添加显着降低了角叉菜胶薄膜的 WCA 从 61.1 ± 5.4 ° 到 37.2 ± 2.1 °,Fe 3 O 4 -Ag 和 Fe 3 O 4 @NH 2 -Ag 的添加降低了 WCA薄膜在较小程度上(分别为 56.9 ± 4.6 ° 和 56.9 ± 4.6 °)。的Fe 3 ö 4 NP也改善卡拉胶的热稳定性,在铁3 ö 4 @NH 2 -Ag(22℃对13℃)和UV阻挡性质(T 280,0.1±0.0%和3.3±1.5% )。

更新日期:2021-09-01
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