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Recent Advances on Annulation Reactions with Allyl and Propargyl Sulfonium Salts
Synthesis ( IF 2.6 ) Pub Date : 2021-08-04 , DOI: 10.1055/a-1578-2911
Jun-Long Li , Qing-Zhu Li , Wen-Lin Zou , Zhi-Qiang Jia

Allyl and propargyl sulfonium salts are readily available reagents that have recently emerged as versatile building blocks for the assembly of cyclic skeletons. As an alternative to classical sulfonium salts, allyl and propargyl sulfonium salts can be converted into the corresponding vinyl sulfur ylide or allenic sulfonium salt intermediates that contain diverse nucleophilic or electrophilic reactive positions, thereby enabling a great variety of annulation reactions. In this short review, we provide a comprehensive overview of the recent developments in this growing field by summarizing annulation reactions involving allyl and propargyl sulfonium salts. 1 Introduction2 Annulations with Allyl Sulfonium Salts3 Annulations with Propargyl Sulfonium Salts4 Conclusion

中文翻译:

烯丙基和炔丙基锍盐环化反应的最新进展

烯丙基和炔丙基锍盐是现成的试剂,最近已成为组装环状骨架的通用构件。作为经典锍盐的替代品,烯丙基和炔丙基锍盐可以转化为相应的乙烯基硫叶立德或丙二烯锍盐中间体,这些中间体含有不同的亲核或亲电反应位点,从而实现多种环化反应。在这篇简短的评论中,我们通过总结涉及烯丙基和炔丙基锍盐的环化反应,全面概述了这一不断发展的领域的最新发展。1 简介2 烯丙基锍盐的环化3 炔丙基锍盐的环化4 结论
更新日期:2021-08-31
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