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Palladium-catalyzed carbonylative synthesis of 3-arylquinolin-2(1H)-ones from benzyl chlorides and o-nitrobenzaldehydes
Molecular Catalysis ( IF 4.6 ) Pub Date : 2021-08-30 , DOI: 10.1016/j.mcat.2021.111842 Jian-Li Liu 1 , Chen-Yang Hou 1 , Xinxin Qi 1 , Xiao-Feng Wu 2
中文翻译：
钯催化从苄基氯和邻硝基苯甲醛羰基化合成 3-芳基喹啉-2(1H)-酮
更新日期：2021-08-30
Molecular Catalysis ( IF 4.6 ) Pub Date : 2021-08-30 , DOI: 10.1016/j.mcat.2021.111842 Jian-Li Liu 1 , Chen-Yang Hou 1 , Xinxin Qi 1 , Xiao-Feng Wu 2
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A palladium-catalyzed carbonylative cyclization of benzyl chlorides with o-nitrobenzaldehydes has been developed for the synthesis of 3-arylquinolin-2(1H)-ones. Mo(CO)6 played a dual role as both a CO surrogate and a reductant in this carbonylative transformation.
中文翻译：
钯催化从苄基氯和邻硝基苯甲醛羰基化合成 3-芳基喹啉-2(1H)-酮
已经开发了钯催化的苄基氯与邻硝基苯甲醛的羰基化环化反应，用于合成 3-芳基喹啉-2(1 H )-酮。Mo(CO) 6在该羰基化转化中扮演着CO替代物和还原剂的双重角色。
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