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Eco-friendly Biowaste-based natural surfactant for lyotropic assemblies and Bio-adsorbent for dye removal
Inorganic Chemistry Communications ( IF 3.8 ) Pub Date : 2021-08-28 , DOI: 10.1016/j.inoche.2021.108871
Aditya Goyal 1 , Prayas Singh 1 , Pankaj Chamoli 2 , K.K. Raina 3 , Ravi K. Shukla 1
Affiliation  

Aggregation behavior of biowaste Litchi Chinensis (LC) seed in three different solvents of varying polarity [water (80), formamide (1 0 8), and glycerol (37)] has been studied. Nematic liquid crystalline phase has been obtained for studied systems as confirmed by a polarizing optical microscope (POM). Potential of the LC seeds has been checked to remove the Rhodamine B (RhB) dye from the wastewater. Effect of dye varying concentration (1 mg/L, 3 mg/L, 5 mg/L, 7 mg/L and 10 mg/L) varying pH (3,6 and 9), and contact time (0 to120 sec) on adsorption process have been evaluated. About 52% of dye removal efficiency is achieved with bare 50 mg adsorbent at pH≈ 6. Pseudo-first-order kinetics is found best fitted for the adsorption process (R2~0.98). Freundlich isotherm is found best fitted to the adsorption data which is also vindicated by a greater value of R2~0.95. Hydrogen bonding, electrostatic interactions, and pi-pi interaction between RhB and LC seeds (saponin) could be responsible for the adsorption process. These results indicate that LC seed can act as a perfect surfactant for lyotropic assemblies and also an effectual natural adsorbent for the dye adsorption and cleaning of aquatic systems.



中文翻译:

用于溶致组装的环保生物废物天然表面活性剂和用于染料去除的生物吸附剂

已经研究了生物废物荔枝 (LC) 种子在三种不同极性的溶剂 [水 (80)、甲酰胺 (1  0  8) 和甘油 (37)] 中的聚集行为。通过偏光显微镜 (POM) 证实,研究系统已获得向列液晶相。已经检查了 LC 种子从废水中去除罗丹明 B (RhB) 染料的潜力。染料不同浓度(1 mg/L、3 mg/L、5 mg/L、7 mg/L 和 10 mg/L)、不同 pH(3,6 和 9)和接触时间(0 到 120 秒)的影响吸附过程进行了评价。在 pH≈6 时使用 50mg 吸附剂可实现约 52% 的染料去除效率。发现伪一级动力学最适合吸附过程 (R 2~0.98)。发现 Freundlich 等温线最适合吸附数据,R 2 ~0.95的更大值也证明了这一点。RhB 和 LC 种子(皂苷)之间的氢键、静电相互作用和 pi-pi 相互作用可能是吸附过程的原因。这些结果表明,LC 种子可以作为一种完美的溶致组装表面活性剂,也是一种有效的天然吸附剂,用于染料吸附和水生系统的清洁。

更新日期:2021-09-27
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