Journal of Sol-Gel Science and Technology ( IF 2.5 ) Pub Date : 2021-08-27 , DOI: 10.1007/s10971-021-05623-w Neslihan Turan 1 , Pınar Oruç 1 , Yeşim Demirölmez 1 , Ayten Seçkin 1 , Ali Orkun Çağırtekin 1 , Sukru Cavdar 1 , Haluk Koralay 1 , Nihat Tuğluoğlu 2
Zn0.95Co0.05O was synthesized by sol-gel method and then Zn0.95Co0.05O pellet was prepared to investigate its structural, morphological, electrical, and impedance properties. For this purpose, the pellet was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and impedance measurement techniques. SEM images showed that the particle sizes of Zn0.95Co0.05O were between 1 and 100 μm. The frequency and temperature dependence of capacitance, conductance, and complex impedance characteristics of Zn0.95Co0.05O in a pellet form were investigated within the temperature range of 300–500 K and frequency range of 1 kHz–1.5 MHz. The radii of the semicircular arc reduced with increasing temperature revealing that the Zn0.95Co0.05O shows negative temperature coefficient of resistance as in semiconductors. The impedance analysis revealed the contribution of grains and grain boundaries to the conduction and polarization processes.
中文翻译:
块体Zn0.95Co0.05O的温度相关电阻和阻抗特性研究
锌0.95钴0.05 O的通过溶胶-凝胶法合成,然后锌0.95钴0.05制备Ò粒料来调查其结构,形态,电气和阻抗特性。为此,通过扫描电子显微镜 (SEM)、X 射线衍射 (XRD) 和阻抗测量技术对颗粒进行表征。SEM图像显示Zn 0.95 Co 0.05 O的粒径在1和100μm之间。Zn 0.95 Co 0.05的电容、电导和复阻抗特性的频率和温度依赖性在 300-500 K 的温度范围和 1 kHz-1.5 MHz 的频率范围内研究了颗粒形式的 O。半圆弧的半径随着温度的升高而减小,这表明Zn 0.95 Co 0.05 O 显示出与半导体一样的负电阻温度系数。阻抗分析揭示了晶粒和晶界对传导和极化过程的贡献。