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A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce2P2W16O60L2}n zipper chains
CrystEngComm ( IF 3.1 ) Pub Date : 2021-08-23 , DOI: 10.1039/d1ce00896j Wenyan Wang 1 , Natalya V. Izarova 1, 2 , Jan van Leusen 1 , Paul Kögerler 1, 2
CrystEngComm ( IF 3.1 ) Pub Date : 2021-08-23 , DOI: 10.1039/d1ce00896j Wenyan Wang 1 , Natalya V. Izarova 1, 2 , Jan van Leusen 1 , Paul Kögerler 1, 2
Affiliation
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{α2,
-P2W16O60} polyoxotungstate cluster units featuring phenylphosphonates and CeIII ions embedded into the segregated lacunary sites of the cluster shell organize into the first coordination polymer of a polyoxometalate functionalized by both organophosphonate and lanthanoid. Inter-cluster Ce–O![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
W links result in double-chains, with {CeIII2(α2,
-PV2WVI16O60)L2} cluster units oriented alternatingly perpendicular to the chain propagation direction, akin to the protruding teeth of a zipper.
中文翻译：
膦酸盐-镧系元素多金属氧酸盐配位聚合物：{Ce2P2W16O60L2}n拉链链
{α 2 ,-P 2 W 16 O 60 } 聚氧钨酸簇单元，其特征是苯基膦酸盐和 Ce III离子嵌入簇壳的隔离空隙位点，组织成第一个由有机膦酸盐和镧系元素官能化的多金属氧酸盐的配位聚合物。簇间 Ce-O W 链接导致双链，{Ce III 2 (α 2 , -P V 2 W VI 16 O 60 )L 2} 簇单元交替地垂直于链的传播方向，类似于拉链的突出齿。
更新日期：2021-08-27
-P2W16O60} polyoxotungstate cluster units featuring phenylphosphonates and CeIII ions embedded into the segregated lacunary sites of the cluster shell organize into the first coordination polymer of a polyoxometalate functionalized by both organophosphonate and lanthanoid. Inter-cluster Ce–OW links result in double-chains, with {CeIII2(α2,-PV2WVI16O60)L2} cluster units oriented alternatingly perpendicular to the chain propagation direction, akin to the protruding teeth of a zipper.
中文翻译：
膦酸盐-镧系元素多金属氧酸盐配位聚合物：{Ce2P2W16O60L2}n拉链链
{α 2 ,
-P 2 W 16 O 60 } 聚氧钨酸簇单元，其特征是苯基膦酸盐和 Ce III离子嵌入簇壳的隔离空隙位点，组织成第一个由有机膦酸盐和镧系元素官能化的多金属氧酸盐的配位聚合物。簇间 Ce-O W 链接导致双链，{Ce III 2 (α 2 , -P V 2 W VI 16 O 60 )L 2} 簇单元交替地垂直于链的传播方向，类似于拉链的突出齿。
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