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Single-Step Pore-Selective Silver-Functionalized Honeycomb-Patterned Porous Polystyrene Film Using a Modified Breath Figure Method
Macromolecular Research ( IF 2.4 ) Pub Date : 2021-08-24 , DOI: 10.1007/s13233-021-9070-z
Shahkar Falak 1 , Bo Kyoung Shin 1 , Do Sung Huh 1
Affiliation  

A fabrication strategy for the pore-selective functionalization of silver (Ag) in the honeycomb-patterned (HCP) porous polystyrene (PS) film was demonstrated by a modified breath figure method accompanying an interfacial chemical reaction. It was performed by casting the polymer solution including ferrocene under humid conditions containing AgNO3. The film showed HCP porous morphology with pore-selective Ag coating. The coating of Ag was identified by scanning electron microscopy with energy-dispersive X-ray spectroscopy and elemental mapping analysis. The conductivity of the film was obtained by a four-point probe conductivity measuring method, and it was observed that the conductivity increased by increasing the ferrocene, concentration.



中文翻译:

单步孔选择性银功能化蜂窝状多孔聚苯乙烯薄膜使用改良的呼吸图方法

通过伴随界面化学反应的改良呼吸图方法证明了蜂窝图案 (HCP) 多孔聚苯乙烯 (PS) 膜中银 (Ag) 孔选择性功能化的制备策略。它通过在含有AgNO 3 的潮湿条件下浇铸含有二茂铁的聚合物溶液来进行。该薄膜显示出具有孔选择性 Ag 涂层的 HCP 多孔形态。Ag 涂层通过扫描电子显微镜、能量色散 X 射线光谱和元素映射分析进行鉴定。通过四点探针电导率测量方法获得薄膜的电导率,观察到电导率随着二茂铁浓度的增加而增加。

更新日期:2021-08-25
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