ABSTRACT

Isosorbide is a biobased compound which could become in the near future an advantageous competitor of petroleum-derived components in the synthesis of polymers of different nature. When the reactivity of isosorbide is not enough, it can be successfully transformed into secondary building blocks, such as isosorbide bis(methyl carbonate), which provides extra functionalities for polymerization reactions with diols or diamines. The present review summarizes the possibilities for isosorbide as a green raw material to be used in the synthesis of polycarbonates and polyurethanes to obtain products of similar or enhanced properties to the commercial equivalents.

中文翻译：

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异山梨醇作为聚碳酸酯和聚氨酯的基本成分的未来

摘要

异山梨醇是一种生物基化合物，在不久的将来，它可能成为不同性质聚合物合成中石油衍生成分的有利竞争者。当异山梨醇的反应性不够时，它可以成功转化为二级结构单元，如异山梨醇双（碳酸甲酯），为与二醇或二胺的聚合反应提供额外的功能。本综述总结了异山梨醇作为绿色原料用于合成聚碳酸酯和聚氨酯以获得与商业等效物相似或增强的产品的可能性。