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Electrical property improvement of phenolic formaldehyde resin with graphene and ionic liquid
Korean Journal of Chemical Engineering ( IF 2.7 ) Pub Date : 2021-08-15 , DOI: 10.1007/s11814-021-0860-y
Hong Wang 1 , Shan-Shan Yao 2 , Fan-Long Jin 2 , Zhifu Guan 3 , Soo-Jin Park 4
Affiliation  

The ionic liquid 3-decyl-bis(1-vinyl-1H-imidazole-3-ium-bromide) (C10[VImBr]2) was synthesized and its chemical structure characterized by Fourier-transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. To improve the electrical conductivity of the phenolic formaldehyde (PF) resin, PF/graphene and PF/graphene/C10[VImBr]2 composites were prepared via a melt blending and compression-curing process. The impact strength of the composites was shown to increase with the addition of increasing proportion of graphene, and with increasing proportion of C10[VImBr]2, of up to 5 wt%. In detail, the electrical conductivity of the PF/graphene composites increased significantly from 2.3×10−12 to 4×10−4S/cm as the graphene content increased from 0 to 20 wt%. Moreover, the electrical conductivity of the PF/graphene/C10[VImBr]2 composites containing 15 wt% graphene was shown to increase from 5.6×10−5 to 9.2×10−4 S/cm as the content of C10[VImBr]2 increased from 0 to 5 wt%.



中文翻译:

石墨烯和离子液体对酚醛树脂电性能的改善

合成了离子液体3-癸基-双(1-乙烯基-1H-咪唑-3-溴化鎓)(C 10 [VImBr] 2 ),并通过傅里叶变换红外光谱和1 H核磁表征了其化学结构。共振光谱。为了提高酚醛(PF)树脂的导电性,通过熔融共混和压缩固化工艺制备了PF/石墨烯和PF/石墨烯/C 10 [VImBr] 2复合材料。复合材料的冲击强度随着石墨烯比例的增加和C 10 [VImBr] 2比例的增加而增加, 高达 5 wt%。具体而言,随着石墨烯含量从0增加到20wt% ,PF/石墨烯复合材料的电导率从2.3×10 -12显着增加到4×10 -4 S/cm。此外,PF /石墨烯/ C的电导率10 [VImBr] 2层包含复合材料15%(重量)的石墨烯显示出从5.6×10增加-5至9.2×10 -4 S /厘米为C的含量10 [VImBr ] 2从 0 增加到 5 重量%。

更新日期:2021-08-19
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