Hydrofluoroolefin (HFO) gases are state-of-the-art cooling agents with widespread household and industrial applications. Considering their structural benefits these fluorous feedstocks have gained the attention of organic chemists in the last couple of years. In this short review we summarized the existing synthetic transformations of these gaseous starting material and present their applicability in the synthesis of fluorine-containing organic molecules, which have potential importance as building blocks and reagents for diverse syntheses.1 Introduction2 Addition Reactions3 Substitutions4 Organometallic Chemistry4.1 Organolithium Compounds4.2 Organometallic Complexes4.3 Silicon Organic Chemistry4.4 Boron Organic Chemistry4.5 Palladium-Catalyzed Transformations4.6 Metathesis4.7 Hydroesterification, Hydroformylation5 Conclusions

中文翻译：

---

工业相关氢氟烯烃 (HFO) 气体在有机合成中的应用

氢氟烯烃 (HFO) 气体是最先进的冷却剂，具有广泛的家庭和工业应用。考虑到它们的结构优势，这些含氟原料在过去几年中引起了有机化学家的注意。在这篇简短的评论中，我们总结了这些气态起始材料的现有合成转化，并展示了它们在含氟有机分子合成中的适用性，这些分子作为各种合成的构建块和试剂具有潜在的重要性。1 介绍 2 加成反应 3 取代 4 有机金属化学 4。 1 有机锂化合物4.2 有机金属配合物4.3 硅有机化学4.4 硼有机化学4.5 钯催化转化4.6 复分解4.7 加氢酯化、加氢甲酰化5 结论