Aqueous Na-ion batteries have been extensively studied for large-scale energy storage systems. However, their wide application is still limited by their inferior cycle stability (<3000 cycles) and poor temperature tolerance. Furthermore, many of the reported high rate behaviors are achieved at a low mass loading (<3 mg cm⁻²) of the electrodes. Herein, we propose an aqueous Na-ion battery which includes a Ni-based Prussian blue (NiHCF) cathode, a carbonyl-based organic compound, 5,7,12,14-pentacenetetrone (PT) anode and a “water-in-salt” electrolyte (17 mol kg⁻¹ NaClO₄ in water). Its operation involves the reversible coordination reaction of the PT anode and the extraction/insertion of Na⁺ in the NiHCF cathode. It is demonstrated that the wide internal spaces of the PT anode and NiHCF cathode can not only buffer the volumetric change induced by Na⁺ storage, but also enable fast kinetics. The full cell exhibits a supercapacitor-like rate performance of 50 A g⁻¹ (corresponding to a discharge or charge within 6.3 s) and a super-long lifespan of 15,000 cycles. Moreover, the excellent rate performance can still be preserved even with a high mass loading of the electrodes (15 mg_NiHCF cm⁻² and 8 mg_PT cm⁻²). Especially, the cell can work well in a wide temperature range, from −40 to 100 °C, showing a typical all-climate operation.

水系钠离子电池已被广泛研究用于大规模储能系统。然而，它们的广泛应用仍然受到其较差的循环稳定性（<3000 次循环）和较差的温度耐受性的限制。此外，许多报道的高速率行为是在电极的低质量负载（<3 mg cm ^{-2 ）下实现的。}在此，我们提出了一种水系钠离子电池，它包括镍基普鲁士蓝 (NiHCF) 阴极、羰基有机化合物、5,7,12,14-并五苯四酮 (PT) 阳极和“水包”盐”电解质（17 mol kg ^-1 NaClO ₄水溶液）。其操作涉及PT阳极的可逆配位反应和Na ^+的脱嵌在 NiHCF 阴极中。结果表明，PT 阳极和 NiHCF 阴极的宽阔内部空间不仅可以缓冲 Na ⁺存储引起的体积变化，还可以实现快速动力学。全电池表现出50 A g ^-1的类超级电容器倍率性能（对应于6.3 s内的放电或充电）和15,000次循环的超长寿命。此外，即使在电极的高质量负载（15 mg _NiHCF cm ^-2和8 mg _PT cm ^-2）下，仍然可以保持优异的倍率性能。特别是，电池可以在-40至100°C的宽温度范围内良好工作，显示出典型的全气候运行。