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Heterogeneous Olefin Aziridination Reactions Catalyzed by Polymer-Bound Tris(triazolyl)methane Copper Complexes
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2021-08-16 , DOI: 10.1002/ejic.202100526
Manuel R. Rodríguez 1 , Francisco Molina 1 , Pablo Etayo 2 , Miquel A. Pericàs 2, 3 , Pedro J. Pérez 1 , M. Mar Díaz‐Requejo 1
Affiliation  

Efficient olefin aziridination has been achieved with a tris(triazolyl)methane copper catalyst supported onto polystyrene. Aryl, alkyl and methoxycarbonyl-substituted olefins are converted into N-tosylaziridines in good to high yields. The solid catalyst is readily separated by filtration and recycled, allowing its reuse with no significant loss of the catalytic activity.

中文翻译:

聚合物结合的三(三唑基)甲烷铜配合物催化的多相烯烃氮丙啶化反应

用负载在聚苯乙烯上的三(三唑基)甲烷铜催化剂实现了有效的烯烃氮丙啶化。芳基、烷基和甲氧基羰基取代的烯烃以良好至高产率转化为N-甲苯磺酰基丙啶。固体催化剂很容易通过过滤分离和回收,允许其重复使用而不会显着降低催化活性。
更新日期:2021-09-23
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