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ZnO nanoparticles prepared via a green synthesis approach: Physical properties, photocatalytic and antibacterial activity
Journal of Physics and Chemistry of Solids ( IF 4 ) Pub Date : 2021-08-11 , DOI: 10.1016/j.jpcs.2021.110313
Thana Shuga Aldeen 1, 2, 3 , Hamza Elsayed Ahmed Mohamed 1, 2 , Malik Maaza 1, 2
Affiliation  

The aqueous extract of Phoenix roebelenii palm leaves has been utilized for the first time as an effective chelating/stabilizing agent used to synthesize zinc oxide nanoparticles (ZnO NPs) via a green chemistry approach. The physical properties of the nanoparticles were examined using X-ray powder diffraction (XRD), diffuse reflectance spectroscopy (DRS), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED), simultaneous thermogravimetric analysis (TGA) and differential thermal analysis (DTA), photoluminescence (PL) spectroscopy, and Fourier transform infrared (FTIR) spectroscopy. Our XRD investigations revealed that the ZnO NPs have a single phase wurtzite structure with P63mc space group. The crystallite size and lattice strain were calculated using X-ray peak broadening analysis utilizing the Williamson-Hall (W-H) method and were found to be 15.6 nm and 2.1 × 10−3 respectively. The shape of the ZnO NPs was almost spherical, as revealed by TEM analysis. The DRS spectrum showed a direct band gap energy of 3.24 eV. DTA/TGA indicated that the required calcination temperature was 500°C in order to form stable ZnO NPs. PL spectroscopy revealed the presence of weak UV emission related to the free exciton and wide visible-light emission due to oxygen vacancies and other structural defects. The reaction between P. roebelenii palm leaves extract and the zinc precursor was monitored using FTIR spectroscopy at different reaction times. The potential mechanism for the formation of the ZnO NPs using P. roebelenii leaves extract as a natural chelating and stabilizing agent has been discussed. The bioinspired ZnO NPs achieved an outstanding degradation activity of 98% toward methylene blue (MB) dye after 105 min of UV illumination. In addition, the ZnO NPs exhibit a significant bactericidal effect towards gram-positive (Staphylococcus aureus and Streptococcus pneumoniae) and gram-negative (Escherichia coli and Salmonella typhi) pathogenic bacteria.



中文翻译:

通过绿色合成方法制备的氧化锌纳米粒子:物理性质、光催化和抗菌活性

凤梨水提物棕榈叶首次被用作有效的螯合剂/稳定剂,用于通过绿色化学方法合成氧化锌纳米颗粒 (ZnO NPs)。使用 X 射线粉末衍射 (XRD)、漫反射光谱 (DRS)、高分辨率透射电子显微镜 (HRTEM)、选区电子衍射 (SAED)、同步热重分析 (TGA) 和差热分析 (DTA)、光致发光 (PL) 光谱和傅里叶变换红外 (FTIR) 光谱。我们的 XRD 研究表明,ZnO NPs 具有 P63mc 空间群的单相纤锌矿结构。-3分别。TEM 分析表明,ZnO NPs 的形状几乎是球形的。DRS 光谱显示直接带隙能量为 3.24 eV。DTA/TGA 表明所需的煅烧温度为 500°C,以形成稳定的 ZnO NP。PL 光谱揭示了由于氧空位和其他结构缺陷,存在与自由激子和宽可见光发射相关的弱紫外发射。在不同反应时间使用 FTIR 光谱监测P. roebelenii棕榈叶提取物和锌前体之间的反应。使用P. roebelenii形成 ZnO NPs 的潜在机制已经讨论了作为天然螯合剂和稳定剂的叶提取物。在紫外线照射 105 分钟后,仿生的 ZnO NPs 对亚甲蓝 (MB) 染料的降解活性达到了 98%。此外,ZnO NPs 对革兰氏阳性(金黄色葡萄球菌和肺炎链球菌)和革兰氏阴性(大肠杆菌伤寒沙门氏菌)病原菌表现出显着的杀菌作用。

更新日期:2021-08-20
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