In recent years, defect-engineered Zr-based UiO-66 metal-organic frameworks (UiO-66(Zr) metal-organic frameworks (MOFs)) have shown huge advantages in catalytic, functional materials, adsorption, and other fields due to their large surface areas, well-ordered porous structures, and flexible tailorability. It is extremely challenging to introduce defect sites in the synthesis of MOFs to regulate the physicochemical properties of materials such as (energy band structure, pore structure, etc.) to obtain an excellent performance. This paper reviews the recent research results of synthesis methods, characterization technologies, and application fields of defect-engineered UiO-66(Zr) MOFs materials in order to provide new insights to synthesize high-performance UiO-66(Zr) MOFs materials and promote the development of UiO-66(Zr) in various fields.

近年来，缺陷工程化的 Zr 基 UiO-66 金属有机骨架（UiO-66（Zr）金属有机骨架（MOFs））由于其在催化、功能材料、吸附等领域显示出巨大的优势。大表面积、有序的多孔结构和灵活的可剪裁性。在 MOF 的合成中引入缺陷位点来调节材料的物理化学性质（如能带结构、孔结构等）以获得优异的性能极具挑战性。本文综述了近年来缺陷工程UiO-66(Zr) MOFs材料的合成方法、表征技术和应用领域的研究成果，以期为合成高性能UiO-66(Zr) MOFs材料和促进UiO-66(Zr)在各个领域的发展。