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Assessment of different kinetic models of carbon dioxide transformation to methanol via hydrogenation, over a Cu/ZnO/Al2O3 catalyst
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.8 ) Pub Date : 2021-08-06 , DOI: 10.1007/s11144-021-02045-1
Leila Samiee 1 , Esmaeil GhasemiKafrudi 1
Affiliation  

In the work presented here, the feasibility study of the methanol production from pure CO2 and H2 has been conducted. This study focused on investigation of the previous kinetic models used for methanol synthesis by hydrogenation process at different processing conditions such as: pressure, temperature, catalyst loading and molar ratio of H2 to CO2 to select the best one. The results showed that, the combined rate expression containing both CO and CO2 hydrogenation terms would result in the better yield. Besides, it was found that the reactor containing recycle mood ensures a higher efficiency up to 65% methanol yield at the range of (200–250 °C) and 50 bar. The kinetic model based on CO and CO2 hydrogenation along with the proposed configuration showed the reasonable methanol yield in a practical methanol plant as much as 41%.



中文翻译:

评估在 Cu/ZnO/Al2O3 催化剂上通过加氢将二氧化碳转化为甲醇的不同动力学模型

在这里介绍的工作中,进行了从纯 CO 2和 H 2生产甲醇的可行性研究。本研究的重点是研究以前用于通过加氢工艺合成甲醇的动力学模型,例如:压力、温度、催化剂负载和 H 2与 CO 2 的摩尔比,以选择最佳模型。结果表明,包含CO和CO 2加氢项的组合速率表达式将导致更好的产率。此外,发现包含循环模式的反应器可确保在 (200–250 °C) 和 50 bar 范围内实现高达 65% 的甲醇产率的更高效率。基于 CO 和 CO 2的动力学模型 加氢以及建议的配置表明,在实际甲醇工厂中,合理的甲醇产率高达 41%。

更新日期:2021-08-10
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