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Revised parametrization of the recombination velocity at SiO2/SiNx-passivated phosphorus-diffused surfaces
Solar Energy Materials and Solar Cells ( IF 6.9 ) Pub Date : 2021-08-06 , DOI: 10.1016/j.solmat.2021.111292
Andreas Wolf 1 , Julian Egle 1 , Sebastian Mack 1 , Hannes Höffler 1 , David Herrmann 1 , Sabrina Lohmüller 1 , Jörg Horzel 1 , Andreas Fell 1, 2
Affiliation  

We investigate the effective surface recombination velocity Seff of alkaline textured, Phosphorus-diffused and thermal SiO2/SiNx passivated surfaces with an emphasis on the impact of the thermal oxidation temperature. The application of a recent calibration procedure for the carrier lifetime measurements enables a precise determination of the dark saturation current density. The experimental results include 25 diffusion/oxidation process combinations that cover a wide range of final surface concentration levels Ns between 3⋅1020 cm−3 and 1⋅1019 cm−3, using oxidation temperatures Tox from 650 °C to 900 °C. This yields a data set that enables a revision of the commonly applied parameterization of the effective surface recombination velocity of this passivation scheme using numerical simulation. In addition, the impact of fixed surface charges is modeled for separating field effect and chemical passivation properties. Also, the role of the oxidation temperature on the passivation quality is investigated.



中文翻译:

SiO2/SiNx 钝化磷扩散表面复合速度的修正参数化

我们研究了碱性织构、磷扩散和热 SiO 2 /SiN x钝化表面的有效表面复合速度S eff,重点是热氧化温度的影响。最近的载流子寿命测量校准程序的应用能够精确确定暗饱和电流密度。实验结果包括覆盖宽范围的最终表面浓度水平的25扩散/氧化工艺组合Ñ小号3⋅10之间20 厘米-3和1⋅10 19 厘米-3,使用氧化温度Ť从 650 °C 到 900 °C。这产生了一个数据集,可以使用数值模拟来修改该钝化方案的有效表面复合速度的常用参数化。此外,对固定表面电荷的影响进行建模以分离场效应和化学钝化特性。此外,还研究了氧化温度对钝化质量的影响。

更新日期:2021-08-07
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