Porphyrins and related macrocycles have been studied broadly for their applications in medicine and materials because of their tunable physicochemical, optoelectronic and magnetic properties. In this review article, we focused on the applications of fluorinated porphyrinoids and their supramolecular systems and summarized the reports published on these chromophores in the past 5-6 years. The commercially available fluorinated porphyrinoids: meso-perfluorophenylporphyrin (TPPF₂₀) perfluorophthalocyanine (PcF₁₆) and meso-perfluorophenylcorrole (CorF₁₅) have increased photo and oxidative stability due to the presence of fluoro groups. Because of their tunable properties and robustness toward oxidative damage these porphyrinoid-based chromophores continue to gain attention of researchers developing advanced functional materials for applications such as sensors, photonic devices, component for solar cells, biomedical imaging, theranostics and catalysts.

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氟卟啉的应用：更新†

卟啉和相关的大环化合物因其可调节的物理化学、光电和磁性特性而在医学和材料中的应用得到了广泛的研究。在这篇综述文章中，我们重点介绍了氟化卟啉及其超分子系统的应用，并总结了过去5-6年发表的关于这些发色团的报道。市售的氟化类卟啉：内消旋全氟苯基卟啉 (TPPF ₂₀ ) 全氟酞菁 (PcF ₁₆ ) 和内消旋全氟苯基考罗 (CorF ₁₅) 由于氟基团的存在而增加了光稳定性和氧化稳定性。由于它们的可调节特性和对氧化损伤的稳健性，这些基于卟啉的发色团继续受到研究人员的关注，他们正在开发用于传感器、光子器件、太阳能电池组件、生物医学成像、治疗诊断学和催化剂等应用的先进功能材料。