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Ni0.25Co0.75O nanowire array supported on Cu@CuO foam, an inexpensive and durable catalyst for hydrogen generation from ammonia borane
Catalysis Communications ( IF 3.7 ) Pub Date : 2021-08-01 , DOI: 10.1016/j.catcom.2021.106343
Yufa Feng 1, 2 , Fei Lv 3 , Huize Wang 2 , Xiaodong Chen 2 , Hang Li 2 , Zhiyu Chen 2 , Guangyu Lin 2 , Jinyun Liao 2 , Mingyang He 1 , Quanbing Liu 4
Affiliation  

The development of highly active and stable catalysts is desirable for hydrogen generation from ammonia borane (AB). In this study, Ni0.25Co0.75O nanowire array supported on Cu@CuO foam (Ni0.25Co0.75O/Cu@CuO) has been successfully fabricated. The Ni0.25Co0.75O/Cu@CuO catalyst exhibited high performance towards AB hydrolysis with a high hydrogen generation rate (HGR) of 4.348 Lhydrogen min−1 gcat.−1. More importantly, the activity of Ni0.25Co0.75O/Cu@CuO has only decreased slightly after twelve cycles. This work provides a simple method to fabricate an inexpensive film catalyst with high activity and good stability for ammonia borane hydrolysis.



中文翻译:

负载在 Cu@CuO 泡沫上的 Ni0.25Co0.75O 纳米线阵列,一种廉价且耐用的氨硼烷制氢催化剂

开发高活性和稳定的催化剂是氨硼烷(AB)制氢所需要的。在这项研究中,已成功制造出负载在 Cu@CuO 泡沫上的Ni 0.25 Co 0.75 O 纳米线阵列(Ni 0.25 Co 0.75 O/Cu@CuO)。Ni 0.25 Co 0.75 O/Cu@CuO 催化剂对 AB 水解表现出高性能,具有 4.348 Lmin -1 g cat的高产氢率 (HGR) -1。更重要的是,Ni 0.25 Co 0.75的活性O/Cu@CuO 在十二个循环后仅略有下降。这项工作提供了一种简单的方法来制备廉价的薄膜催化剂,该催化剂具有高活性和良好的氨硼烷水解稳定性。

更新日期:2021-08-12
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