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H2O treatment-induced uniform NiOX interfacial layer boosting brightness and light-emitting efficiency of blue perovskite electroluminescence
Organic Electronics ( IF 3.2 ) Pub Date : 2021-07-31 , DOI: 10.1016/j.orgel.2021.106299
Hailong Wang 1, 2 , Yushuai Xu 1, 2 , Liang Chen 1 , Jiang Wu 1, 2 , Qian Wang 1, 2 , Baohua Zhang 3 , Zhiyuan Xie 1, 2
Affiliation  

The reported NiOx interfacial layers in blue perovskite light-emitting diodes (PeLEDs) usually require high-temperature annealing and complex interface modification. Herein, we report a kind of uniform NiOx anode interfacial layer induced by H2O treatment, which effectively enhances the brightness and light-emitting efficiency of blue PeLEDs simultaneously. Compared to the as-prepared NiOx anode interfacial layer, H2O treatment renders uniform and pinhole-free NiOx morphology. The solution-processed perovskite blue emissive layer prepared atop the H2O-treated NiOx interfacial layer demonstrates enhanced photoluminescent property and superior morphology with low trap density. The blue PeLEDs employing H2O-treated NiOx as anode interfacial layer show a maximum luminance of 9052 cd/m2 and a maximum external quantum efficiency (EQE) of 1.80%, whereas the control device based on the as-prepared NiOx anode interfacial layer merely exhibits a maximum luminance of 3850 cd/m2 and an EQE of 0.88%, leading to about 135% and 104% increase in brightness and efficiency, respectively. The PeLEDs emit pure blue light with emission peak located at 482 nm and demonstrate superior spectral stability under different driving voltages and operating time.



中文翻译:

H2O 处理诱导均匀 NiOX 界面层提高蓝色钙钛矿电致发光的亮度和发光效率

据报道,蓝色钙钛矿发光二极管(PeLED)中的NiO x界面层通常需要高温退火和复杂的界面改性。在此,我们报告了一种通过 H 2 O 处理诱导形成的均匀 NiO x阳极界面层,它同时有效地提高了蓝色 PeLED 的亮度和发光效率。与所制备的 NiO x阳极界面层相比,H 2 O 处理呈现出均匀且无针孔的 NiO x形态。在 H 2 O 处理的 NiO x 上制备的溶液处理的钙钛矿蓝色发光层界面层表现出增强的光致发光性能和具有低陷阱密度的优异形态。采用 H 2 O 处理的 NiO x作为阳极界面层的蓝色 PeLED显示出 9052 cd/m 2的最大亮度和 1.80% 的最大外部量子效率 (EQE),而基于所制备的 NiO x的控制装置阳极界面层仅表现出 3850 cd/m 2的最大亮度和 0.88% 的 EQE,分别导致亮度和效率增加约 135% 和 104%。PeLED 发出纯蓝光,发射峰位于 482 nm,在不同的驱动电压和工作时间下表现出卓越的光谱稳定性。

更新日期:2021-08-04
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