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Preparation and properties of bismaleimide resin blended with alkynyl-terminated modifiers
High Performance Polymers ( IF 2.1 ) Pub Date : 2021-07-30 , DOI: 10.1177/09540083211034118
Hui Zhang 1 , Linxiang Wang 2 , Qiaolong Yuan 1 , Qing Zheng 2 , Liqiang Wan 1 , Farong Huang 1
Affiliation  

A kind of modified bismaleimide resin, with good processability, heat resistance, and impact strength was developed, using 4,4-dipropargyloxydiphenyl ether (DPEDPE), N-(4-propargyloxyphenyl)maleimide (4-PPM), and 3-ethynylphenyl maleimide (3-EPM) as modifiers. The DPEDPE, 4-PPM, and 3-EPM were synthesized and characterized by Fourier transform infrared spectroscopy (FTIR) and 1H-nuclear magnetic resonance (1H NMR), and used to modify the N,N-(4,4-diphenylmethane)bismaleimide (BDM)/2,2-diallyl bisphenol A (DABPA) resin system (BD) to obtain the different blend resin systems of DPEDPE-modified BD (BDD), 4-PPM-modified BD (BDP), and 3-EPM-modified BD (BDE). The curing temperature of BD resin increases with increase of the alkynyl-terminated modifier content. The processability of BD resin was improved with addition of the propargyloxy-terminated compounds. The temperature of 5% weight loss, residual yield at 800°C and glass transition temperature of the cured BD resin increase with increase of the alkynyl-terminated modifier content and can reach 443°C, 46.7% and higher than 380°C. The tensile strength of the cured BD resin decreases with increase of alkynyl-terminated modifier content. The impact strength of the cured BD resin increases with increase of the propargyloxy-terminated compound content and can increase by 65%. The tensile strength, elastic modulus, and impact strength of the cured BD resin blended with DPEDPE can be 73.7 MPa, 4.1 GPa, and 19.6 kJ m−2, respectively. Moreover, the cured BD resin blended with DPEDPE has good water absorption resistance.



中文翻译:

炔基封端改性剂共混双马来酰亚胺树脂的制备及性能

一类改性双马来酰亚胺树脂,具有良好的加工性,耐热性和冲击强度的开发,使用4,4 ' -dipropargyloxydiphenyl醚(DPEDPE),ñ - (4-炔丙氧基)马来酰亚胺(4-PPM),和3-乙炔基苯基马来酰亚胺 (3-EPM) 作为改性剂。DPEDPE、4-PPM 和 3-EPM 被合成并通过傅里叶变换红外光谱 (FTIR) 和1 H-核磁共振 ( 1 H NMR)表征,并用于修饰N,N ' -(4,4 ' -二苯基甲烷)双马来酰亚胺(BDM)/2,2 '-二烯丙基双酚A(DABPA)树脂体系(BD)得到DPEDPE改性BD(BDD)、4-PPM改性BD(BDP)和3-EPM改性BD(BDE)的不同共混树脂体系。BD树脂的固化温度随着炔基改性剂含量的增加而增加。BD树脂的加工性能随着炔丙氧基封端化合物的加入而得到改善。固化后BD树脂的5%失重温度、800℃残余收率和玻璃化转变温度随着端炔基改性剂含量的增加而升高,可达443℃,46.7%,高于380℃。固化后的 BD 树脂的拉伸强度随着炔基封端改性剂含量的增加而降低。固化后的BD树脂的冲击强度随着炔丙氧基封端化合物含量的增加而增加,可增加65%。-2,分别。此外,与DPEDPE共混的固化BD树脂具有良好的抗吸水性。

更新日期:2021-08-01
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