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Accelerated CO2 transport by synergy effect of ionic liquid and Zn particles
Journal of Industrial and Engineering Chemistry ( IF 6.1 ) Pub Date : 2021-07-29 , DOI: 10.1016/j.jiec.2021.07.034
Seung Yeon Rhyu 1 , Sang Wook Kang 1, 2
Affiliation  

In this experiment, an ionic liquid (BMIMBF4) was used to prepare a composite membrane containing ZnO nanoparticles. Our previous study indicated that a composite membrane composed of ZnO and the ionic liquid (BMIMBF4) showed high CO2/N2 separation performance with a GPU of 101 and a selectivity of 42.1. The oxide layer of ZnO nanoparticles with the imidazolium ring of ionic liquid (BMIMBF4) increased the solubility of CO2 and acted as a barrier for N2, leading to an overall improvement in the performance. However, the liquid film was absorbed into support over time and became thickened, leading to instability. In order to solve this problem, a solid polymer composite film was manufactured and investigated as a solution. The polymer PEBAX2533 was used as a polymer matrix to produce a composite membrane capable of showing both high separation performance and long-term stability.



中文翻译:

通过离子液体和锌颗粒的协同作用加速 CO2 传输

在该实验中,使用离子液体(BMIMBF 4)制备含有ZnO纳米颗粒的复合膜。我们之前的研究表明,由 ZnO 和离子液体 (BMIMBF 4 )组成的复合膜显示出高 CO 2 /N 2分离性能,GPU 为 101,选择性为 42.1。具有离子液体咪唑环 (BMIMBF 4 )的 ZnO 纳米颗粒的氧化物层增加了 CO 2的溶解度并作为 N 2的屏障,从而导致性能的整体改进。然而,随着时间的推移,液膜被吸收到载体中并变厚,导致不稳定。为了解决这个问题,制造并研究了固体聚合物复合膜作为解决方案。聚合物 PEBAX2533 被用作聚合物基质来生产复合膜,该膜能够同时显示出高分离性能和长期稳定性。

更新日期:2021-09-04
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