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Application of supported lanthanum catalysts in the hydrogenation of nitriles
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.8 ) Pub Date : 2021-07-29 , DOI: 10.1007/s11144-021-02028-2
Kinga Juhász 1 , Krisztina Lévay 1 , László Hegedűs 1 , Diána Balogh-Weiser 1, 2 , Zoltán Hell 1 , Laurence Pirault-Roy 3
Affiliation  

Nickel and lanthanum on MgO or MgO–Al2O3 catalysts were prepared and characterized. The applicability of the catalysts was studied in the liquid-phase hydrogenation of benzonitrile. A La/MgO catalyst showed surprisingly high activity and selectivity. The scope of the reaction was extended to other nitriles (benzyl cyanide, cinnamonitrile, adiponitrile) over this La/MgO catalyst.



中文翻译:

负载型镧催化剂在腈加氢中的应用

镍和镧在 MgO 或 MgO-Al 2 O 3催化剂上的制备和表征。研究了催化剂在苄腈液相加氢中的适用性。La/MgO 催化剂显示出惊人的高活性和选择性。在这种 La/MgO 催化剂上,反应范围扩展到其他腈类(苄基氰、肉桂腈、己二腈)。

更新日期:2021-07-29
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