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Evading strength-corrosion tradeoff in Mg alloys via dense ultrafine twins
Nature Communications ( IF 16.6 ) Pub Date : 2021-07-29 , DOI: 10.1038/s41467-021-24939-3
Changjian Yan 1, 2 , Yunchang Xin 1 , Xiao-Bo Chen 3 , Daokui Xu 4 , Paul K Chu 5 , Chaoqiang Liu 6 , Bo Guan 7 , Xiaoxu Huang 7 , Qing Liu 1
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Conventional ultrafine-grains can generate high strength in Mg alloys, but significant tradeoff of corrosion resistance due to inclusion of a large number of non-equilibrium grain boundaries. Herein, an ultrafine-grain structure consisting of dense ultrafine twins is prepared, yielding a high strength up to 469 MPa and decreasing the corrosion rate by one order of magnitude. Generally, the formation of dense ultrafine twins in Mg alloys is rather difficult, but a carefully designed multi-directional compression treatment effectively stimulates twinning nucleation within twins and refines grain size down to 300 nm after 12-passes compressions. Grain-refinement by low-energy twins not only circumvents the detrimental effects of non-equilibrium grain boundaries on corrosion resistance, but also alters both the morphology and distribution of precipitates. Consequently, micro-galvanic corrosion tendency decreases, and severe localized corrosion is suppressed completely. This technique has a high commercial viability as it can be readily implemented in industrial production.



中文翻译:

通过致密的超细孪晶避免镁合金的强度-腐蚀权衡

传统的超细晶粒可以在镁合金中产生高强度,但由于包含大量非平衡晶界,因此在耐腐蚀性方面有显着的权衡。在此,制备了由致密超细孪晶组成的超细晶粒结构,强度高达 469 MPa,腐蚀速率降低一个数量级。通常,在镁合金中形成致密的超细孪晶是相当困难的,但精心设计的多向压缩处理有效地刺激了孪晶内的孪晶形核,并在 12 道次压缩后将晶粒尺寸细化到 300 nm。低能孪晶的晶粒细化不仅避免了非平衡晶界对耐蚀性的不利影响,但也会改变沉淀物的形态和分布。因此,微电偶腐蚀倾向降低,严重的局部腐蚀被完全抑制。该技术具有很高的商业可行性,因为它可以很容易地在工业生产中实施。

更新日期:2021-07-29
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