Formulation of sustainable resource-based organic–inorganic hybrid protective coatings have been achieved using Linseed oil-based silica hybrid with terpolymer (TP) as basic skeletal matrix. The fabrication of TP system was performed by using systematic one pot multi-facile steps (diol fatty amide–linseed oil-based polyester amide TP) synthesis route. The conversion of ester amide functional ends of TP to urethane was initiated to enhance adhesiveness, impermeability, and corrosion resistivity of the processed hybrid material. FT-IR and NMR (¹H, ¹³C, and ²⁹Si) studies help in verifying the chemical structure and progress of the reaction. The formulation of smooth corrosion resistive coating was further analyzed by transmission electron microscopy, scanning electron microscope, and electrochemical corrosion studies. The in-situ tethering and homogeneous dispersion of inorganic moiety in nanoregime throughout the TP system further enhances the stability, wettability, and corrosion protection ability of the nanohybrid vegetable oil-based coating under corrosive environment. High phase angle value at higher frequency end indicates the stability of the coating system. Such coating systems composed of sustainable resource with improved mechanical, thermal, and corrosion protective properties have great potential in future applications.

中文翻译：

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用于防腐涂料的亚麻油衍生的三元共聚物/二氧化硅纳米复合材料

使用亚麻籽油基二氧化硅杂化物和三元共聚物 (TP) 作为基本骨架基质，已经实现了可持续的资源型有机-无机杂化保护涂层的配制。TP系统的制备是通过使用系统的一锅多简便步骤（二醇脂肪酰胺-亚麻籽油基聚酯酰胺TP）合成路线进行的。引发 TP 的酯酰胺官能末端向氨基甲酸酯的转化，以提高加工后的杂化材料的粘合性、不渗透性和耐腐蚀性。FT-IR 和 NMR（¹ H、¹³ C 和²⁹Si) 研究有助于验证反应的化学结构和进程。通过透射电子显微镜、扫描电子显微镜和电化学腐蚀研究进一步分析了光滑耐腐蚀涂层的配方。在原位粘连和在nanoregime无机部分的均匀分散在整个TP系统进一步增强了稳定性，润湿性，和防腐蚀保护的纳米杂化植物油基涂层的腐蚀环境下的能力。高频端的高相位角值表明涂层系统的稳定性。这种由可持续资源组成的涂层系统具有改进的机械、热和腐蚀防护性能，在未来的应用中具有巨大的潜力。