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Magnetic Properties of Layered Rare-Earth Zinc Phosphide HoZn3P3 Prepared under High Pressure
Journal of the Physical Society of Japan ( IF 1.7 ) Pub Date : 2021-07-27 , DOI: 10.7566/jpsj.90.094701
Janagan Saravanan 1 , Hariharan Ponmani 1 , Yuya Sato 1 , Jun-ichi Hayashi 1 , Yukihiro Kawamura 1 , Hirotada Gotou 2 , Chihiro Sekine 1
Affiliation  

The magnetic properties of the two-dimensional triangular-lattice compound HoZn3P3 synthesized under high pressure are reported. We have performed magnetization, electrical resistivity, and specific heat measurements of the compound. The magnetic susceptibility shows an anomaly at around 5 K attributed to a magnetic ordering. The resistivity reveals metallic behavior and a minimum at around 17 K (Tmin); then, an upturn of the resistivity below Tmin shows a logarithmic dependence of the temperature (−log T). Furthermore, the resistivity exhibits a sharp drop at 4.5 K, which corresponds to the magnetic ordering. The upturn of the resistivity at low temperatures was suppressed by a magnetic field. The specific heat shows a clear peak at TM = 4.5 K due to the magnetic ordering. The TM shifts towards a high temperature at a rate of 0.06 K/kOe. A large γ value of 199 mJ/mol K2 was observed, and the γ value increases as the magnetic field increases and shows a maximum at 60 kOe. We demonstrate the crucial role of the hybridization between 4f electrons and conduction electrons depending on the distance between rare-earth R atoms in determining the transport and magnetic properties of RZn3P3.

中文翻译:

高压制备层状稀土磷化锌HoZn3P3的磁性能

报道了在高压下合成的二维三角晶格化合物HoZn 3 P 3的磁性能。我们已经对化合物进行了磁化、电阻率和比热测量。磁化率在 5 K 附近显示异常,这归因于磁排序。电阻率显示出金属行为,并且在 17 K ( T min )附近具有最小值;然后,低于T min的电阻率上升显示温度的对数依赖性(-log T)。此外,电阻率在 4.5 K 处急剧下降,这对应于磁序。低温下电阻率的上升被磁场抑制。由于磁性有序,比热在T M = 4.5 K处显示出明显的峰值。所述Ť中号朝0.06 K /千奥斯特的速率高的温度变化。观察到199 mJ/mol K 2的大γ值,γ值随着磁场的增加而增加,并在 60 kOe 处出现最大值。我们证明了 4 f电子和传导电子之间杂化的关键作用取决于稀土R之间的距离原子在确定R Zn 3 P 3的传输和磁性能中。
更新日期:2021-07-27
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