The self-assembly process of block copolymers (BCPs) in solution has been at the focus of extended scientific research over the past several decades owing to the astonishing morphological diversity and attainable complexity of the resulting nanoassemblies, including spheres, cylinders, lamellae, vesicles, and many other complex, bicontinuous or even hierarchical structures. The ever-increasing sophistication in the development of synthetic chemistry methods and techniques has led to a myriad of available macromolecules with varying chemical compositions, architectures, features, and properties. This assortment of characteristics has led in turn to a plethora of intriguing self-organized polymeric nanostructures, with countless possible applications in several nanotechnological fields relevant to physics, chemistry, material science, nanomedicine, and biomaterials. The present review aims to illuminate the importance and fascinating potential of BCPs solution self-assembly by highlighting recent advances and emerging trends in the field, as well as significant application-oriented progress, through characteristic contemporary examples.

中文翻译：

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嵌段共聚物溶液自组装：最新进展、新兴趋势和应用

在过去的几十年里，由于所得纳米组件惊人的形态多样性和可达到的复杂性，嵌段共聚物 (BCP) 在溶液中的自组装过程一直是科学研究的重点，包括球体、圆柱体、薄片、囊泡、以及许多其他复杂的、双连续的甚至层次结构。合成化学方法和技术发展的日益复杂导致了无数具有不同化学成分、结构、特征和性质的可用大分子。这种各种各样的特性反过来又导致了大量有趣的自组织聚合物纳米结构，在与物理、化学、材料科学、纳米医学、和生物材料。本综述旨在通过典型的当代例子强调该领域的最新进展和新兴趋势，以及面向应用的重大进展，阐明 BCPs 解决方案自组装的重要性和迷人潜力。