Porphyrin chemistry is Shakespearean: over a century of study has not withered the field’s apparently infinite variety. Heme proteins continually astonish us with novel molecular mechanisms, while new porphyrin analogues bowl us over with unprecedented optical, electronic, and metal-binding properties. Within the latter domain, corroles occupy a special place, exhibiting a unique and rich coordination chemistry. The 5d metallocorroles are arguably the icing on that cake.

中文翻译：

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5d Metallocorroles 的故事：从金属配体错配到癌症光治疗的新基石

卟啉化学是莎士比亚式的：一个多世纪的研究并没有使该领域看似无限的多样性枯萎。血红素蛋白不断以新的分子机制让我们惊讶，而新的卟啉类似物则以前所未有的光学、电子和金属结合特性让我们震惊。在后一个领域，corroles 占有特殊的地位，表现出独特而丰富的配位化学。5d metallocorroles 可以说是锦上添花。