Gas-phase structure, bonding, and fragmentation chemistry of the An (IV)–TMPDCAM complexes studied using mass spectrometry and theoretical calculation (An = Th and U),Rapid Communications in Mass Spectrometry

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Gas-phase structure, bonding, and fragmentation chemistry of the An (IV)–TMPDCAM complexes studied using mass spectrometry and theoretical calculation (An = Th and U)
Rapid Communications in Mass Spectrometry ( IF 2 ) Pub Date : 2021-07-21 , DOI: 10.1002/rcm.9168
Zhixin Xiong _{1,

2} , Jingwen Hu _{1,

2} , Xiuting Chen ₁

Affiliation

Pyridine-2,6-dicarboxamides (PDCAMs) exhibit a certain extraction ability for tetravalent actinide ions, but quite limited information regarding the structures and reactivities of the corresponding An⁴⁺-PDCAMs complexes is available. Neutral diamides can form multiply charged complexes with lanthanide and actinide cations, which are well suited for gas-phase investigations using electrospray ionization (ESI) mass spectrometry in conjunction with theoretical calculation.

中文翻译：

使用质谱和理论计算研究 An (IV)-TMPDCAM 复合物的气相结构、键合和碎裂化学（An = Th 和 U）

Pyridine-2,6-dicarboxamides (PDCAMs) 对四价锕系离子具有一定的萃取能力，但关于相应 An ⁴⁺ -PDCAMs 复合物的结构和反应性的信息非常有限。中性二酰胺可以与镧系元素和锕系元素阳离子形成多电荷配合物，非常适合使用电喷雾电离 (ESI) 质谱和理论计算进行气相研究。

更新日期：2021-08-05

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