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Thermal Conduction of Elastomeric Polyurethanes with Titanium Dioxide as Mineral Filler and its Composites with Recycled Kevlar Fabric
Fibre Chemistry ( IF 0.5 ) Pub Date : 2021-07-16 , DOI: 10.1007/s10692-021-10236-8
J. Quagliano Amado 1 , H. Alvarez 2 , E. Moreno 2 , M. Sanchez 2 , G. Escobar 2
Affiliation  

Thermal conduction of composites made from Kevlar® fabric and polyurethane (PU) mineral-filled elastomers was studied. Contact heat conduction was measured according to ISO 12127 standard (which measures the threshold time required for a 10°C increase throughout the sample). PU elastomer filled with TiO2 did not show significant differences in the threshold time for heat conduction as compared to neat PU elastomer although the values tended to be lower. The maximal threshold time was obtained for PU elastomer with TiO2 (125 s for a sample 8 mm wide). No significant differences in the threshold time were observed for other PU elastomers with either TiO2 filler or two added organic fire retardants. Composites made of both Kevlar® fabric/PU and Kevlar®/PU/Kevlar® complied with ISO 15538:2001 standard for firefighter clothing. The aim was to determine if recycled Kevlar® fabric could replace Nomex®, poly(m-phenylene isophthalamide), a costly material of choice in the textile industry for firefighter structural suits.



中文翻译:

以二氧化钛为矿物填料的弹性聚氨酯的热传导及其与再生芳纶织物的复合材料

研究了由 Kevlar ®织物和聚氨酯 (PU) 矿物填充弹性体制成的复合材料的热传导。根据 ISO 12127 标准测量接触热传导(测量整个样品温度升高 10°C 所需的阈值时间)。与纯 PU 弹性体相比,填充有 TiO 2 的PU 弹性体在热传导的阈值时间方面没有表现出显着差异,尽管这些值往往较低。对于含有 TiO 2 的PU 弹性体,获得了最大阈值时间(8 毫米宽的样品为 125 秒)。对于具有 TiO 2填料或两种添加的有机阻燃剂的其他 PU 弹性体,未观察到阈值时间的显着差异。由两种芳纶制成的复合材料®面料/PU 和 Kevlar ® /PU/Kevlar ®符合 ISO 15538:2001 消防服标准。目的是确定回收的 Kevlar ®织物是否可以替代 Nomex ®聚(间苯二甲酰胺),这是纺织行业用于消防员结构服的昂贵材料。

更新日期:2021-07-16
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