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Chemically Stable Metal–Organic Frameworks: Rational Construction and Application Expansion
Accounts of Chemical Research ( IF 18.3 ) Pub Date : 2021-07-14 , DOI: 10.1021/acs.accounts.1c00280
Tao He 1 , Xiang-Jing Kong 1 , Jian-Rong Li 1
Affiliation  

Metal–organic frameworks (MOFs) have been attracting tremendous attention owing to their great structural diversity and functional tunability. Despite numerous inherent merits and big progress in the fundamental research (synthesizing new compounds, discovering new structures, testing associated properties, etc.), poor chemical stability of most MOFs severely hinders their involvement in practical applications, which is the final goal for developing new materials. Therefore, constructing new stable MOFs or stabilizing extant labile MOFs is quite important. As with them, some “potential” applications would come true and a lot of new applications under harsh conditions can be explored. Efficient strategies are being pursued to solve the stability problem of MOFs and thereby achieve and expand their applications.

中文翻译:

化学稳定的金属-有机骨架:合理构建和应用扩展

金属有机框架(MOFs)由于其巨大的结构多样性和功能可调性而引起了极大的关注。尽管在基础研究(合成新化合物、发现新结构、测试相关性质等)方面有许多固有的优点和重大进展,但大多数 MOF 的化学稳定性差严重阻碍了它们在实际应用中的参与,这是开发新化合物的最终目标。材料。因此,构建新的稳定 MOF 或稳定现有的不稳定 MOF 非常重要。与它们一样,一些“潜在”应用将成为现实,并且可以探索恶劣条件下的许多新应用。正在寻求有效的策略来解决 MOF 的稳定性问题,从而实现和扩展其应用。
更新日期:2021-08-03
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