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Visible-light-induced ruthenium-catalyzed alkylation of activated C(sp3)−H bonds
Chem Catalysis Pub Date : 2021-07-15 , DOI: 10.1016/j.checat.2021.05.015
Olivier Baslé 1
Affiliation  

In this issue of Chem Catalysis, Koenigs and co-workers report an efficient photocatalytic system for activated C(sp3)−H bond functionalization at room temperature. This approach, based on visible-light-induced ruthenium catalysis, allows for selective αC−H alkylation of amides under mild reaction conditions.



中文翻译:

可见光诱导的钌催化活化的 C(sp 3 )-H 键烷基化

在本期Chem Catalysis 中,Koenigs 及其同事报道了一种在室温下用于活化 C(sp 3 )-H 键功能化的高效光催化系统。这种基于可见光诱导的钌催化的方法允许在温和的反应条件下选择性地对酰胺进行 αC-H 烷基化。

更新日期:2021-07-15
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