当前位置: X-MOL 学术J. Porphyr. Phthalocyanines › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Temperature effects on structure: Six-coordinate [Fe(TPP)(1-MeIm)(CO)]
Journal of Porphyrins and Phthalocyanines ( IF 1.5 ) Pub Date : 2020-05-20 , DOI: 10.1142/s1088424619501372
Nathan J. Silvernail 1 , W. Robert Scheidt 1
Affiliation  

We have examined the effects of changing the temperature on the structure of a six-coordinate (tetraphenylporphinato)iron(II) complex, [Fe(TPP)(1-MeIm)(CO)] C6H6. In particular, we examined whether the coordination group parameters, i.e. the Fe–C and C–O parameters showed any effects. The study, carried out between 100 and 330 K, revealed no effect on those coordination group parameters. The axial Fe–N(Im) bond distance showed a small effect. The peripheral phenyl groups show a somewhat larger bond distance effect with bond distance increases of 0.02 to 0.03 Å. The population of the disordered solvent molecule favors one site as the temperature is lowered.

中文翻译:

温度对结构的影响:六坐标 [Fe(TPP)(1-MeIm)(CO)]

我们已经研究了改变温度对六配位 (四苯基卟啉) 铁 (II) 配合物 [Fe(TPP)(1-MeIm)(CO)] C 结构的影响6H6. 特别是,我们检查了协调组参数是否,一世.e. Fe-C 和 C-O 参数显示出任何影响。该研究在 100 到 330 K 之间进行,显示对这些协调组参数没有影响。轴向 Fe-N(Im) 键距显示出小的影响。外围苯基显示出更大的键距效应,键距增加 0.02 到 0.03 Å。随着温度的降低,无序溶剂分子的数量有利于一个位点。
更新日期:2020-05-20
down
wechat
bug