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William Crowell Bray and the discovery of the first periodic homogeneous reaction in 1921
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.8 ) Pub Date : 2021-07-12 , DOI: 10.1007/s11144-021-02019-3
Rinaldo Cervellati 1
Affiliation  

This review is a deep study of the Bray’s 1921 paper that reported the observation of the first periodic reaction in homogeneous phase. The paper obtained a general indifference by other chemists and some opposition due to the fact that it seemed to contradict the second Principle of Thermodynamics. Only after the work by Ilya Prigogine and coworkers in the mid-1960s, oscillating chemical reactions in the homogeneous phase have been studied intensively, but Bray died in 1946.



中文翻译:

威廉·克罗威尔·布雷 (William Crowell Bray) 和 1921 年第一个周期性均相反应的发现

这篇综述是对 Bray 1921 年论文的深入研究,该论文报道了对均相中第一周期反应的观察。这篇论文得到了其他化学家的普遍冷漠和一些反对,因为它似乎与热力学第二原理相矛盾。只有在 1960 年代中期 Ilya Prigogine 及其同事的工作之后,才对均相中的振荡化学反应进行了深入研究,但布雷于 1946 年去世。

更新日期:2021-07-13
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