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Magnetic Circularly Polarized Luminescence in the Photoexcited States of Racemic [n]Helicenes (n=3–5,7) in Tetrahydrofuran and Dimethyl Sulfoxide Solutions
ChemPhysChem ( IF 2.9 ) Pub Date : 2021-07-12 , DOI: 10.1002/cphc.202100346
Hayato Toda 1 , Shuhei Otake 2 , Akari Ito 2 , Makoto Miyasaka 2 , Michiya Fujiki 3 , Yoshitane Imai 1
Affiliation  

Racemic [n]helicenes at the photoexcited state under 1.6 T reveals circular polarization in the order of 0.1 % T−1 at the room temperature. The magnetic circularly polarized luminescence sign can be inverted by choosing Faraday geometry and [n]-number with/without methoxy groups.
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中文翻译:

在四氢呋喃和二甲基亚砜溶液中外消旋 [n] Helicenes (n=3–5,7) 的光激发态下的磁性圆偏振发光

在 1.6 T光激发态下的外消旋 [n] 螺旋烯在室温下显示出 0.1 % T -1数量级的圆极化。可以通过选择法拉第几何形状和 [n] 数(带/不带甲氧基)来反转磁性圆偏振发光符号。
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更新日期:2021-07-12
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