当前位置: X-MOL 学术Synlett › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
NiCl2 as a Cheap and Efficient Precatalyst for the Coupling of Aryl Fluorosulfonate and Phosphite
Synlett ( IF 2 ) Pub Date : 2021-06-08 , DOI: 10.1055/a-1524-4912
Shengmei Guo , Hu Cai , Wenjie Yan , Hongbo Zhou , Haoyuan Li , Huimin Hu , Ying Yu

Herein, NiCl2 was employed as a cheap precatalyst in the formation of C(sp2)-P bond via cross coupling reaction of phenol derivates and phosphine oxides/phosphites. This method allows a variety of phenols with diverse functional groups to transform to phosphates with good yields. No additional additive was used in this reaction.

中文翻译:

NiCl2 作为一种廉价高效的预催化剂用于芳基氟磺酸酯和亚磷酸酯的偶联

在此,NiCl2 被用作廉价的预催化剂,通过苯酚衍生物和氧化膦/亚磷酸酯的交叉偶联反应形成 C(sp2)-P 键。该方法允许具有不同官能团的多种酚以良好的产率转化为磷酸盐。在该反应中没有使用额外的添加剂。
更新日期:2021-07-09
down
wechat
bug