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Conduction mechanism in rare earth-doped perovskite material through impedance analysis
Bulletin of Materials Science ( IF 1.8 ) Pub Date : 2021-07-05 , DOI: 10.1007/s12034-021-02489-0
Sweta Sharma 1 , M D Soaib Khan 2 , Rajeev Ranjan 2 , Yogesh Kumar 3
Affiliation  

Perovskite (PVSK) has been considered as a promising material for electrochemical energy storage devices. In this paper, the conduction mechanism of rare earth europium-doped perovskite material, Pb1−xEux (Zr0.60Ti0.40)1−x/4O3 as an electrode material for solar cell as well as supercapacitor has been studied. The structural and electrical properties were studied at room temperature for different compositions of Eu-doped PVSK, x = 0.00, 0.03, 0.06 and 0.09. Europium-doped PVSK was prepared via solid-state technique in the higher range of temperature. Structural and surface morphologies were done by X-ray diffraction and SEM. The electrical property has been studied via CIS technique at different frequencies. Study of ac conductivity and impedance analysis affirms PVSK as a potential material for the electrode of photo supercapacitor, a device which helps in the conversion of light energy into electrical and which also helps in energy storage mechanism.



中文翻译:

通过阻抗分析稀土掺杂钙钛矿材料的导电机制

钙钛矿(PVSK)被认为是一种很有前途的电化学储能装置材料。本文研究了稀土铕掺杂钙钛矿材料Pb 1− x Eu x (Zr 0.60 Ti 0.40 ) 1− x /4 O 3作为太阳能电池和超级电容器电极材料的导电机制。在室温下研究了不同组成的 Eu 掺杂 PVSK 的结构和电学性能,x= 0.00、0.03、0.06 和 0.09。铕掺杂PVSK是通过固态技术在较高温度范围内制备的。结构和表面形态通过 X 射线衍射和 SEM 完成。已通过 CIS 技术在不同频率下研究了电气特性。交流电导率和阻抗分析的研究证实 PVSK 是光电超级电容器电极的潜在材料,这种器件有助于将光能转化为电能,也有助于储能机制。

更新日期:2021-07-05
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