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Upgrading of the aqueous product stream from hydrothermal liquefaction: Simultaneous removal of minerals and phenolic components using waste-derived hydrochar
Biomass & Bioenergy ( IF 6 ) Pub Date : 2021-07-01 , DOI: 10.1016/j.biombioe.2021.106170
Sanette Marx , Roelf J. Venter , Amoné Louw , Christine T. Dewah

We investigated the co-adsorption of AAEM and phenolic components onto hydrochar prepared from the organic fraction of MSW. HCl washing of the char removed more AAEM (up to 1 g L−1) than phenols from the hydrochar and improved the oxygen content from 21.31% to 24.9%. A relationship between the number and type of functional groups of phenolic components determined the order of adsorption: guaiacol > phenol > vanillyl alcohol > resorcinol. For AAEM the order of adsorption was Ca2+ (103 mg g−1) > K+ (95.7 mg g−1) > Na+ (8.7 mg g−1) > Mg2+ (3.4 mg g−1). Removal efficiency increased with an increase in initial adsorbate concentration with values of 94, 94, 91 and 91% (base on original mass present) obtained for Ca2+, K+, Mg2+, and Na+, respectively. Hydrochar could remove 100% of guaiacol, phenol and resorcinol present and 61% of vanillyl alcohol in the presence of AAEMs. The Dubinin-Radushkevich isotherm best fitted the multilayer adsorption of phenolic components with a calculated qmax of 68.7 mg g−1 and 50.3 mg g−1 for vanillyl alcohol and resorcinol respectively. Henry's law best described the adsorption of AAEMs. A mass transfer analysis showed that film diffusion controls the adsorption process at low adsorbate concentrations (Bi < 100). At higher initial sorbate concentration, the rate of transport was controlled by intra-particle diffusion.

AAEM components were exchanged for phenolic components to form stronger hydrogen bonds, resulting in initial preferential adsorption of phenolics with AAEM only adsorbing at higher initial concentrations.



中文翻译:

水热液化的含水产品流的升级:使用废物衍生的水炭同时去除矿物质和酚类成分

我们研究了 AAEM 和酚类成分在由 MSW 有机部分制备的氢化碳上的共吸附。炭的 HCl 洗涤从氢化炭中去除了比苯酚更多的 AAEM(高达 1 g L -1),并将氧含量从 21.31% 提高到 24.9%。酚类成分的官能团数量和类型之间的关系决定了吸附顺序:愈创木酚>苯酚>香草醇>间苯二酚。对于 AAEM,吸附顺序为 Ca 2+ (103 mg g -1 ) > K + (95.7 mg g -1 ) > Na + (8.7 mg g -1 ) > Mg 2+ (3.4 mg g -1)。去除效率随着初始吸附物浓度的增加而增加,Ca 2+、K +、Mg 2+和 Na + 的值分别为 94、94、91 和 91%(基于原始质量)。Hydrochar 可以在 AAEM 存在下去除 100% 的愈创木酚、苯酚和间苯二酚以及 61% 的香草醇。Dubinin-Radushkevich 等温线最适合酚类成分的多层吸附,计算出的 q max为 68.7 mg g -1和 50.3 mg g -1分别为香草醇和间苯二酚。亨利定律最好地描述了 AAEM 的吸附。传质分析表明,薄膜扩散在低吸附物浓度(Bi < 100)下控制吸附过程。在较高的初始山梨酸盐浓度下,传输速率由颗粒内扩散控制。

AAEM 组分与酚类组分交换以形成更强的氢键,导致酚类物质的初始优先吸附,而 AAEM 仅在较高的初始浓度下吸附。

更新日期:2021-07-01
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