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Borylation of azines via a Minisci-type reaction
Chem ( IF 23.5 ) Pub Date : 2021-06-29 , DOI: 10.1016/j.chempr.2021.06.013 Shengbiao Yang , Juntao Ye
中文翻译:
通过 Minisci 型反应对吖嗪进行硼酸化
更新日期:2021-07-08
Chem ( IF 23.5 ) Pub Date : 2021-06-29 , DOI: 10.1016/j.chempr.2021.06.013 Shengbiao Yang , Juntao Ye
C–H borylation of N-heteroarenes is an efficient yet highly challenging route to borylated aromatics. In a recent issue of Nature, Leonori and co-workers demonstrated a novel strategy toward this end by utilizing a boryl-radical-based Minisci-type reaction that shows orthogonal site selectivity to transition-metal-catalyzed approaches.
中文翻译:
通过 Minisci 型反应对吖嗪进行硼酸化
N-杂芳烃的 C-H 硼化是一种有效但极具挑战性的硼化芳烃途径。在最近一期的《自然》杂志上,Leonori 及其同事通过利用基于硼基自由基的 Minisci 型反应展示了一种实现这一目标的新策略,该反应对过渡金属催化方法显示出正交位点选择性。