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Investigation of EG-Bi2S3 nanorods photocatalytic activity under visible light for dye degradation from aquatic system
Environmental Science and Pollution Research ( IF 5.8 ) Pub Date : 2021-06-22 , DOI: 10.1007/s11356-021-14933-z
Subramanian Keerthana 1 , Rathinam Yuvakkumar 1 , Ponnnusamy Senthil Kumar 2, 3 , Ganesan Ravi 1 , Dhayalan Velauthapillai 4 , Dai-Viet Nguyen Vo 5
Affiliation  

Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3 were synthesized by employing solvothermal route. X-ray diffraction, UV-vis absorption, photoluminescence, Raman, scanning electron microscopic studies confirmed the structural, optical, morphological behaviors. The XRD pattern of Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3 was correlated well with JCPDS # 65-2435. The crystallite size was found to be 57, 49, and 40 nm. The photoluminescence spectra showed semiconducting property of prepared Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3. The absorption spectra of Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3 nanorods were well matched with the spectra of a previous report. The bandgap values of Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3 were calculated to be 1.56, 1.45, and 1.3 eV in reducing order. The morphology of Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3 samples showed the development of nanorods. The 10 ml EG-Bi2S3 sample showed better development of nanorods with the addition of ethylene glycol. The agglomeration was considerably reduced with the mixing of solvent. Bi2S3, 5 ml EG-Bi2S3, and 10 ml EG-Bi2S3 catalysts were added to the methylene blue dye solution and its photocatalytic properties were investigated by reducing toxic pollutants under light. The 10 ml EG-Bi2S3 sample with neutral pH and 0.1 g of catalyst was added and investigated which showed 86% of efficiency towards dye degradation. The narrow bandgap, defined morphology of 10 ml EG-Bi2S3, made a positive result towards efficient photocatalytic activity.



中文翻译:

EG-Bi2S3 纳米棒在可见光下对水生系统染料降解的光催化活性研究

Bi 2 S 3、5ml EG-Bi 2 S 3和10ml EG-Bi 2 S 3通过溶剂热法合成。X射线衍射、紫外-可见吸收、光致发光、拉曼、扫描电镜研究证实了其结构、光学、形貌行为。Bi 2 S 3、5ml EG-Bi 2 S 3和10ml EG-Bi 2 S 3的XRD图与JCPDS#65-2435相关性良好。发现微晶尺寸为 57、49 和 40 nm。光致发光光谱表明制备的Bi 2 S 3具有半导体性质, 5 毫升 EG-Bi 2 S 3和 10 毫升 EG-Bi 2 S 3Bi 2 S 3、5 ml EG-Bi 2 S 3和10 ml EG-Bi 2 S 3纳米棒的吸收光谱与先前报告的光谱非常匹配。Bi 2 S 3、5ml EG-Bi 2 S 3和10ml EG-Bi 2 S 3的带隙值按递减顺序计算为1.56、1.45和1.3eV。Bi 2 S 3的形态,5 ml EG-Bi 2 S 3, 和 10 ml EG-Bi 2 S 3样品显示纳米棒的发展。10 ml EG-Bi 2 S 3样品显示在添加乙二醇的情况下更好地发展纳米棒。随着溶剂的混合,结块明显减少。将Bi 2 S 3、5 ml EG-Bi 2 S 3和10 ml EG-Bi 2 S 3催化剂加入到亚甲基蓝染料溶液中,通过在光照下减少有毒污染物来研究其光催化性能。10 ml EG-Bi 2 S 3添加具有中性 pH 值和 0.1 g 催化剂的样品并进行研究,结果显示染料降解效率为 86%。10 ml EG-Bi 2 S 3的窄带隙、确定的形态对有效的光催化活性产生了积极的结果。

更新日期:2021-06-22
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