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Preparation and Characterization of Graphenedoped Molybdenum Trioxide/Manganese Oxide Ternary Nanocomposite for Supercapacitor Performance
Brazilian Journal of Physics ( IF 1.6 ) Pub Date : 2021-06-16 , DOI: 10.1007/s13538-021-00940-5
Kalpana R , Ashokan S , Subbaramaniyan P , Shanmugasundaram P , Sudha D , Thennarasu S , Jesbin J

A novel MoO3, MoO3/GO, and MoO3/GO/MnO2 ternary nanocomposites have been prepared by hydrothermal technique. The samples are characterized to identify the various performances such as structural, morphological, elemental, and surface area analysis. XRD data reveals that the MoO3 nanoparticles show orthorhombic crystal structures and their miller indices are in good agreement with the standard value (0 2 0), (1 1 0), (0 4 0), and (0 2 1) crystalline planes of MoO3. SEM images show the formation of stacked graphene oxide (GO) and spherical nanocrystallites. The presence of molybdenum (Mo), manganese (Mn), and oxide (O) are confirmed from the EDS spectrum. BET result exposing high surface area with more active sites for redox process of the materials, which giving rise to a better catalytic activity. Electrochemical performances of MoO3/GO/MnO2 ternary nanocomposite exhibited a tiny area of hysteresis, clearly revealing the enhanced specific capacitance of the material. The calculated specific capacitance value is 89.5 F g−1. Thus, the prepared ternary nanocomposites give a gateway for new potential industrial applications.



中文翻译:

用于超级电容器性能的石墨烯掺杂三氧化钼/氧化锰三元纳米复合材料的制备和表征

采用水热技术制备了新型MoO 3、MoO 3 /GO和MoO 3 /GO/MnO 2三元纳米复合材料。对样品进行表征以识别各种性能,例如结构、形态、元素和表面积分析。XRD数据表明,MoO 3纳米颗粒显示正交晶体结构,其米勒指数与标准值(0 2 0)、(1 1 0)、(0 4 0)和(0 2 1)晶面非常吻合MoO 3. SEM 图像显示了堆叠的氧化石墨烯 (GO) 和球形纳米微晶的形成。EDS 光谱证实了钼 (Mo)、锰 (Mn) 和氧化物 (O) 的存在。BET 结果暴露出具有更多活性位点的高表面积,用于材料的氧化还原过程,从而产生更好的催化活性。MoO 3 /GO/MnO 2三元纳米复合材料的电化学性能表现出微小的滞后区域,清楚地揭示了材料的增强的比电容。计算出的比电容值为89.5 F g -1。因此,制备的三元纳米复合材料为新的潜在工业应用提供了途径。

更新日期:2021-06-17
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