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Reverse orientation in the ultrasound-assisted [3 + 2]-cycloaddition reaction of nitrile imines with 3-formylchromone-Meldrum’s acid adducts
Molecular Diversity ( IF 3.8 ) Pub Date : 2021-06-15 , DOI: 10.1007/s11030-021-10240-4
Issa Yavari 1 , Younes Fadakar 1
Affiliation  

The [3 + 2]-cycloaddition reaction of nitrile imines with 2,2-dimethyl-5-[(4-oxo-4H-chromen-3-yl)methylene]-1,3-dioxane-4,6-dione tends to form the reverse-orientation products under ultrasound irradiation in EtOH in the presence of Et3N. Evidence for the structure of product 5b was obtained from single-crystal X-ray analysis.

Graphic abstract



中文翻译:

腈亚胺与 3-甲酰色酮-Meldrum 酸加合物的超声辅助 [3 + 2]-环加成反应中的反向取向

腈亚胺与2,2-二甲基-5-[(4-氧代-4 H-色烯-3-基)亚甲基]-1,3-二恶烷-4,6-二酮的[3 + 2]-环加成反应在Et 3 N存在下,在EtOH 中超声照射下倾向于形成反向取向产物。产物5b的结构的证据是从单晶X 射线分析中获得的。

图形摘要

更新日期:2021-06-15
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