Korean Journal of Chemical Engineering ( IF 2.7 ) Pub Date : 2021-06-15 , DOI: 10.1007/s11814-021-0794-4 Minsoo Kim , Gui-Min Kim , Nianfang Wang , Doh C. Lee
In photocatalysis, photons are absorbed by semiconductor materials and photogenerated electrons and holes migrate to the catalytic surface for desired reactions. Photocatalytic reduction and oxidation of organic molecules pose significant challenges and opportunities, with the surging demand for energy-efficient and carbon-neutral organic synthesis. In this review, we highlight the recent progress in the expanding area of radical-driven photocatalytic transformation of organic molecules. Our focus expands from heterogeneous catalysts to quantum dots, summarizing the reaction mechanism and photocatalytic activity, in reference to conventional molecular catalysts.
中文翻译:
自由基驱动的有机分子光催化转化
在光催化中,光子被半导体材料吸收,光生电子和空穴迁移到催化表面进行所需的反应。随着对节能和碳中性有机合成的需求激增,有机分子的光催化还原和氧化带来了重大挑战和机遇。在这篇综述中,我们重点介绍了自由基驱动的有机分子光催化转化领域不断扩大的最新进展。我们的重点从非均相催化剂扩展到量子点,总结了反应机理和光催化活性,参考了传统的分子催化剂。