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Heavy rare-earth element and Y partitioning between monazite and garnet in aluminous granulites
Contributions to Mineralogy and Petrology ( IF 3.5 ) Pub Date : 2021-06-12 , DOI: 10.1007/s00410-021-01808-2
Shujuan Jiao , Noreen J. Evans , Ross N. Mitchell , Ian C. W. Fitzsimons , Jinghui Guo

Calibrating heavy rare-earth elements (HREE) partitioning between monazite and garnet is a direct way to link datable accessory phases with major minerals, and is therefore vital for the interpretation of geochronological data and the establishment of PTt paths. However, HREE partitioning (DHREE) data for monazite and garnet are lacking for high-temperature–ultrahigh-temperature (HT–UHT: 850–1000 °C) conditions and published data under sub-solidus conditions (600–750 °C) show large variations. We empirically determine DHREE+Y between monazite and garnet that formed during near isobaric cooling along a P–T–t path from ~ 980 °C to 830 °C at ~ 9 kbar from 1.90 to 1.85 Ga from 6 UHT aluminous granulite samples in the Khondalite Belt of North China Craton. The calculated HREE + Y partitioning results overlap at the hand specimen to microdomain scale, implying bulk chemical equilibrium between monazite and garnet. The DY (20 ± 9) and DDy (50 ± 17) can be used to differentiate equilibrated and unequilibrated monazite–garnet pairs, while DGd is indistinguishable and DEr has a large uncertainty. Our newly calibrated DY and DDy, in combination with a compilation of previously published results, indicate different monazite behaviour under sub-solidus and supra-solidus conditions, which might be related to the exhaustion of xenotime. The newly calculated HREE + Y partitioning under HT–UHT conditions can be used as an additional guide to decipher polymetamorphic evolution in high-grade terranes, and provides a basis for future experimental study.



中文翻译:

铝质麻粒岩中独居石和石榴石的重稀土元素和Y分配

校准独居石和石榴石之间的重稀土元素 (HREE) 分配是将可测副相与主要矿物联系起来的直接方式,因此对于解释地质年代学数据和建立P - T - t路径至关重要。然而,缺乏高温-超高温(HT-UHT:850-1000 °C)条件下独居石和石榴石的HREE 分配(D HREE)数据和亚固相线条件(600-750 °C)下的公开数据表现出很大的变化。我们凭经验确定了在沿P-T-t 的近等压冷却过程中形成的独居石和石榴石之间的D HREE+Y华北克拉通孔达岩带中 6 个 UHT 铝麻粒岩样品在约 9 kbar 压力下从 1.90 到 1.85 Ga 从 ~ 980 °C 到 830 °C 的路径。计算出的 HREE + Y 分配结果在手标本到微域尺度上重叠,这意味着独居石和石榴石之间的整体化学平衡。所述d ÿ(20±9)和d(50±17)可被用于区分平衡和非平衡独居石石榴石对,而d的Gd是不可区分和d具有大的不确定性。我们新校准的D YD Dy,结合先前发表的结果汇编,表明在亚固相线和超固相线条件下不同的独居石行为,这可能与磷钇矿的耗尽有关。HT-UHT条件下新计算的HREE+Y分区可作为破译高品位地体多变质演化的额外指南,并为未来的实验研究提供基础。

更新日期:2021-06-13
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