Journal of Physics B: Atomic, Molecular and Optical Physics ( IF 1.6 ) Pub Date : 2021-06-07 , DOI: 10.1088/1361-6455/abf9f0 He Su 1 , Xinlu Cheng 2 , Hong Zhang 1 , Jonathan Tennyson 3
A comprehensive study of electron collisions with the X 1Σg + ground state as well as the metastable A 3Σu + and a 1Πg excited states of the N2molecule is reported using the fixed-nucleus R-matrix method. Integral elastic scattering and electronic excitation cross sections from the X 1Σg + ground state to the eight lowest electronic states, A 3Σu +, B 3Πg, W 3Δu, B′ 3Σu −, a 1Πg, a′ 1Σu −, w 1Δu and C 3Πu, overall agree well with the available experimental and theoretical results although updates of some recommended values are suggested. Accurate electron impact electronic transition cross sections starting from the A 3Σu + and a 1Πg metastable excited states are reported. The total summed electronic transition cross sections from the a 1Πg state is dominant: an order of magnitude higher than those of the X 1Σg + ground state. The de-excitation cross sections generally show a downward trend with increasing incident electron energy, which is different from the elastic and electronic excitation cross sections which generally increase with collision energy. There is a prominent 2Πu symmetry resonance peak at 2.8eV for electronic de-excitation scattering of a 1Πg → B 3Πg, which significantly contributes to the total summed cross sections from the a 1Πg excited state. The present results provide a new insight which will aid understanding of electron spectra in the atmosphere of the Earth and Titan.
中文翻译:
使用 R 矩阵方法与处于基态和电子激发态的分子氮发生电子碰撞
使用固定核 R 矩阵方法报告了对电子与X 1 Σ g +基态以及亚稳态A 3 Σ u +和N 2分子的 1 Π g激发态的碰撞的综合研究。从X 1 Σ g +基态到八个最低电子态A 3 Σ u + , B 3 Π g , W 3 的整体弹性散射和电子激发截面 Δ u , B′ 3 Σ u − , a 1 Π g , a′ 1 Σ u − , w 1 Δ u和C 3 Π u总体上与现有的实验和理论结果一致,尽管建议更新一些推荐值. 从A 3 Σ u +和a 1 Π g开始的精确电子撞击电子跃迁截面报道了亚稳态激发态。来自a 1 Π g状态的总电子跃迁截面总和占主导地位:比X 1 Σ g +基态高一个数量级。退激截面一般随着入射电子能量的增加呈下降趋势,这与弹性和电子激发截面一般随碰撞能量的增加而增加不同。有一个突出的2 Π ù对称共振在2.8eV的峰对的电子去激发散射一个 1个Π克→乙 3 Πg,它对来自a 1 Π g激发态的总横截面有显着贡献。目前的结果提供了一种新的见解,将有助于理解地球和泰坦大气中的电子光谱。