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Alkyl complexes of divalent lanthanides and heavy alkaline earth metals
Russian Chemical Reviews ( IF 7.7 ) Pub Date : 2021-05-24 , DOI: 10.1070/rcr4992
Dmitry O. Khristolyubov 1 , Dmitry M. Lyubov 1 , Alexander A. Trifonov 1, 2
Affiliation  

The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the oxidation state +2 (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba). The synthetic aspects and structural features of this unique class of organometallic compounds, which contain highly reactive M–C bonds, including alkyl, α-silylmethyl, and also benzyl, diphenylmethyl, and triphenylmethyl derivatives are considered.

The bibliography includes 157 references.



中文翻译:

二价镧系元素和重碱土金属的烷基配合物

该综述介绍了氧化态为 +2 的稀土金属烷基衍生物(Sm、Eu、Yb)及其含有重碱土金属(Ca、Sr、Ba)的类似物的合成、结构、反应性和催化活性数据. 考虑了这类独特的有机金属化合物的合成方面和结构特征,其中包含高反应性 M-C 键,包括烷基、α-甲硅烷基甲基以及苄基、二苯甲基和三苯甲基衍生物。

参考书目包括 157 篇参考文献。

更新日期:2021-05-24
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